The breaking of the O-O bond in peroxydisulfuryl difluoride (FO,SOOSO,F) gives FO,SO: (FO2SO)2 2 2 FO2SO The compound on the left of this equation is a colorless liquid that boils at 67.1°C. Its vapor, when heated to about 100°C, turns brown as the product of the reaction forms. Suppose that, in a sample of the vapor, the intensity of the brown color doubles between 100°C and 110°C and that the total pressure increases only by the 2.7% predicted for an ideal gas. Estimate AH° for the preceding reaction.
The breaking of the O-O bond in peroxydisulfuryl difluoride (FO,SOOSO,F) gives FO,SO: (FO2SO)2 2 2 FO2SO The compound on the left of this equation is a colorless liquid that boils at 67.1°C. Its vapor, when heated to about 100°C, turns brown as the product of the reaction forms. Suppose that, in a sample of the vapor, the intensity of the brown color doubles between 100°C and 110°C and that the total pressure increases only by the 2.7% predicted for an ideal gas. Estimate AH° for the preceding reaction.
Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter11: Rate Of Reaction
Section: Chapter Questions
Problem 99QAP: The gas-phase reaction between hydrogen and iodine H2(g)+I22HI(g)proceeds with a rate constant for...
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