The colors in the copper-containing minerals malachite,which is green and has an empirical formula of Cu2CO3(OH)2, and azurite, which is blue and has an empirical formulaof Cu3(CO3)2(OH)2, come from a single d-d transitionin each compound. The compounds are sometimes foundtogether in nature as shown here. (a) What is the electronconfiguration of the copper ion in each mineral? (b) Basedon their colors, in which compound would you predict thecrystal-field splitting Δ is larger?

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds
Section: Chapter Questions
Problem 116QRT
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The colors in the copper-containing minerals malachite,
which is green and has an empirical formula of Cu2CO3
(OH)2, and azurite, which is blue and has an empirical formula
of Cu3(CO3)2(OH)2, come from a single d-d transition
in each compound. The compounds are sometimes found
together in nature as shown here. (a) What is the electron
configuration of the copper ion in each mineral? (b) Based
on their colors, in which compound would you predict the
crystal-field splitting Δ is larger?

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