The concentration of Cl– in a 300.0-mL sample of water drawn from a fresh water acquifer suffering from encroachment of sea water, was determined by titrating with 0.0516 M Hg(NO3)2. The sample was acidified and titrated to the diphenylcarbazone end point, requiring 6.18 mL of the titrant. Report the concentration of Cl– in parts per million
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The concentration of Cl– in a 300.0-mL sample of water drawn from a fresh water acquifer suffering from encroachment of sea water, was determined by titrating with 0.0516 M Hg(NO3)2. The sample was acidified and titrated to the diphenylcarbazone end point, requiring 6.18 mL of the titrant. Report the concentration of Cl–
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- CALCULATE the molarity of NaI in a solution obtained by adding 5 mL of 0.2M NaI to a mixture of 5 mL of 0.2M of K2SO4, 5 mL of K2S2O8, 4mL of H2O and 1 mL of starch.Calculate the amount of caffeine extracted from coffee beans using 1.0215g of the sample. The volume of 0.0252N H2SO4 added to the extract was 25.4 mL, the excess titrated by 21.75 mL of 0.02115N NaOH. Each mL of 0.02 N H2SO4 is equivalent to 3.8858 mg of caffeine (C9H10O2). The percentage of caffeine is:Five white, 500-mg uncoated ascorbic acid (AA) tablets with an average weight of 0.6152-g were pulverized in a mortar. A sample of the powdered ascorbic acid weighing 0.4700-g was placed in an iodine flask and was dissolved in 50-mL H2SO4 then 5-g of KBr was added to the resulting solution. The solution was titrated with 47.81-mL of 0.09640 N STD. KBrO3 to reach a faint yellow endpoint then 3-g KI and 5-mL Starch TS. The blue color solution is then titrated with 2.73-mL of 0.09123 N STD. Na2S2O3 to reach the disappearance of the blue iodostarch complex. MW: KBrO3 = 167.0 ; KIO3 = 214.0 ; Na2S2O3 = 158.11 ; C6H8O6 = 176.12 Compute the milligrams of pure AA per tablet from the assay. 293.3 mg 502.5 mg None of the choices 383.9 mg
- Which of the following are typical impurities in active pharmaceutical ingredients? I. intermediates produced in the synthesis of the API. II. Products of hydrolysis reaction of APIs. III. Residual solvents A) I only B) II only C) III only D) I and III E) I, II, IIIIn the preparation of the standard curve for protein analysis, 50 mn BSA (bovine serum albumin) dissolved in H2O to a final volume of 5 mL was used as stock solution. What is the weight of BSA in 0.1 mL of stock solution? In 0.2 mL?Write the reaction of PCl5 with heavy water.
- A mixture containing only KCl and NaBr is analyzed by the Mohr Method. A 0.3172-g sample is dissolved in 50 mL water and titrated to the Ag2CrO4 endpoint, requiring 36.85 mL of 0.1120 M AgNO3. A blank titration requires 0.71 mL of titrant to reach the same endpoint. Report the % (w/w) KCl and NaBr in the sample. [Answer should be 82.41 % (w /w)]A sample of meat scrap weighing 2.000 g is digested with concentrated sulfuric acid and a catalyst. The resulting solution is made alkaline with NaOH and the liberated ammonia distilled into 50.00 mL of 0.6700 N HCl. The excess acid then requires 30.10 mL of 0.6520 N NaOH for neutralization. What is the percentage of the protein in the meat? The Kjeldahl factor is 6.25.please explain the process and answer Mouthwash acts to clean and disinfect mouths. Two important considerations when designing a mouthwash solution are the pH, which should ideally not be too acidic (where saliva has a normal pH range of 6.2–7.6 and below pH 5.5 erosion may occur), and the resistance of the solution to changes in pH. One example of a buffering system used in mouthwash is based on the compound H3PO4 which has PKa values of 2.1, 7.2 and 12.3. i. Hand-draw the structure of the main phosphorus species at pH 7.0, as well as a balanced equilibrium equation showing the structures of the two main phosphoric acid species at pH 7.0.
- The grid has six lettered boxes, each of which contains an item that may be used to answer the questions that follow. Items may be used more than once and there may be more than one correct item in response to a question. Place the letter(s) of the correct selection(s) on the appropriate line. Could dissolve Zn(OH)2 _____________ Could be used to prepare a buffer from __________ Halfway to the equivalence point in the titration of a weak, monoprotic acid with strong base ________ SO2-related atmospheric phenomenon __________ Species formed by a Lewis acid-base reaction ________ General condition required for precipitation to occur ________ [conj. base] = [conj. acid] in a buffer ___________Apatite, Ca5(PO4)3OH, is the mineral in teeth. On a chemical basis explain why drinking milk strengthens young children’s teeth. Sour milk contains lactic acid. Not removing sour milk from the teeth of young children can lead to tooth decay. Use chemical principles to explain why.After removing the membranes from an eggshell, the shell is dried and its mass recorded as 5.613 g. The eggshell is transferred to a 250–mL beaker and dissolved in 25 mL of 6 N hydrochloric acid solution. After filtering, the solution containing the dissolved eggshell is diluted to 250 mL in a volumetric flask. A 10.00–mL aliquot is placed in a 125–mL Erlenmeyer flask and buffered to a pH of 10. Titrating with 0.04988 M EDTA requires 44.11 mL to reach the end point. Determine the amount of calcium in the eggshell as % w/w calcium carbonate.