The data shown below are Fe(II) concentrations observed at two different depths over an incubation period. They illustrate Fe(II) oxidation in the sediments that were incubated. Time (d) Fe(II) (mM) 0 cm Fe(II) (mM) 45 cm 0.00 13.63 7.39 4.00 2.71 8.04 7.00 0.40 6.97 11.00 0.05 3.93 14.00 0.37 1.66 21.00 0.43 0.59 28.00 0.28 0.37 a) Please calculate the first-order rate constants for Fe(II) oxidation at those two depths. g) please provide the half life for dissolved Fe(II).

Chemistry: Matter and Change
1st Edition
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Chapter16: Reaction Rates
Section: Chapter Questions
Problem 67A
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The data shown below are Fe(II) concentrations observed at two different depths over an incubation period.  They illustrate Fe(II) oxidation in the sediments that were incubated.

Time (d)

Fe(II) (mM) 0 cm

Fe(II) (mM) 45 cm

0.00

13.63

7.39

4.00

2.71

8.04

7.00

0.40

6.97

11.00

0.05

3.93

14.00

0.37

1.66

21.00

0.43

0.59

28.00

0.28

0.37

 

  • a) Please calculate the first-order rate constants for Fe(II) oxidation at those two depths.
  • g) please provide the half life for dissolved Fe(II).
The data shown below are Fe(II) concentrations observed at two different depths over an
incubation period. They illustrate Fe(II) oxidation in the sediments that were incubated.
Time (d)
Fe(II) (mM) 0 cm
Fe(I) (mM) 45 сm
0.00
13.63
7.39
4.00
2.71
8.04
7.00
0.40
6.97
11.00
0.05
3.93
14.00
0.37
1.66
21.00
0.43
0.59
28.00
0.28
0.37
a) Please calculate the first-order rate constants for EFe(II) oxidation at those two depths.
g) please provide the half life for dissolved Fe(II).
Transcribed Image Text:The data shown below are Fe(II) concentrations observed at two different depths over an incubation period. They illustrate Fe(II) oxidation in the sediments that were incubated. Time (d) Fe(II) (mM) 0 cm Fe(I) (mM) 45 сm 0.00 13.63 7.39 4.00 2.71 8.04 7.00 0.40 6.97 11.00 0.05 3.93 14.00 0.37 1.66 21.00 0.43 0.59 28.00 0.28 0.37 a) Please calculate the first-order rate constants for EFe(II) oxidation at those two depths. g) please provide the half life for dissolved Fe(II).
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