The decomposition of aqueous sucrose to form the isomers glucose and fructose is a common organic reaction, which requires a strong catalyst: C12H22O11(aq) + H2O(l) → 2C6H12O6(aq).  The following data were collected during the process: Time (min) [C12H22O11] (mol/L) 0 0.316 39 0.274 80 0.238 140 0.190 210 0.146 Use the following grids to plot three separate graphs of [C12H22O11], ln[C12H22O11], and 1/[C12H22O11] against time to determine the reaction order. (a)Write the rate law expression in its general form (water should not be included). (b)Determine the rate constant with units. (c)Determine the half-life. (d)If we performed a new trial with an initial concentration of sucrose of 0.400 mol/L, what concentration would remain after 4.0 h has passed?

Chemistry: An Atoms First Approach
2nd Edition
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Steven S. Zumdahl, Susan A. Zumdahl
Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 86AE: Sulfuryl chloride (SO2Cl2) decomposes to sulfur dioxide (SO2) and chlorine (Cl2) by reaction in the...
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  1. The decomposition of aqueous sucrose to form the isomers glucose and fructose is a common organic reaction, which requires a strong catalyst: C12H22O11(aq) + H2O(l) → 2C6H12O6(aq).  The following data were collected during the process:

Time (min)

[C12H22O11] (mol/L)

0

0.316

39

0.274

80

0.238

140

0.190

210

0.146

Use the following grids to plot three separate graphs of [C12H22O11], ln[C12H22O11], and 1/[C12H22O11] against time to determine the reaction order.

  1. (a)Write the rate law expression in its general form (water should not be included).



  1. (b)Determine the rate constant with units.



  1. (c)Determine the half-life.



  1. (d)If we performed a new trial with an initial concentration of sucrose of 0.400 mol/L, what concentration would remain after 4.0 h has passed?
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