The deuterated alcohol shown can be converted to an alkyl halide via a mesylate intermediate. Complete the mechanism, draw the final product (with nonbonding electrons) and select the correct absolute stereochemistry of the starting material and the final product. HO H3C-S-CI D O=S=O H Draw curved arrows to form the alkyl halide. Select Draw Templates More Erase
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- ONZ IS ON Determine which substitution mechanism occurs and draw the products, including stereochemistry. + -OCH3 DMSO Br H + CH3OH Br CH,CH, CH3nent/takeCovalentActivity.do?16cal assigi [Review Topics] [References] Use the References to access important values if needed for this question. Draw a structural formula for the major organic anion formed when 2- ethylbutanal is reacted with Tollens' reagent. You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • If no reaction occurs, draw the organic starting material. P. opy aste CH4 ChemDoodle Previous NexDraw the major product(s) of the following reactions, if there is a reaction. Be sure to include stereochemistry in your products. H3C O H;C H3C. CH3 N. CI SOCI2 pyridine OH O=
- Give the major substitution product of the following reaction. a O CH3CO₂H Br heat CH₂ ? O There is no reaction under these conditions or the correct product is not listed here.Draw a structural formula for the major product of the reaction shown. H3C Cl2 H3C H20 Show product stereochemistry IF the reactant alkene has both carbons of the double bond within a ring. • Do not show stereochemistry in other cases. • If the reaction produces a racemic mixture, just draw one stereoisomer. opy aste - [F ChemDoodle Previous NexKelerences Keview topic Draw a structural formula for the major product of the reaction shown. Cl2 H20 CH;CH2CH;CH=CHz • Show product stereochemistry IF the reactant alkene has both carbons of the double bond within a ring. Do not show stereochemistry in other cases. • If the reaction produces a racemic mixture, just draw one stereoisomer. 2reg 2reg M) ots 2reg pts 2req 1 pts 2req 1 pts 2reg ...1 pts ChemDoodle Previous Next> Save and Exit APR tv MacBook Air 80 DII DD F3 F4 FS F6 F7 F8 F10 F1 F12 #3 $ & + 3 4 6. 7 8 %3D dele E Y | { } P [ F G H. J K C V N M ? .. .. * C0 B
- 4. What are the products obtained from the following elimination reaction? Indicate the major product. CH;CH2CCH3 H2O CI 5. a) Determine the major product that is formed when the alkyl halide reacts with a hydroxide ion in an elimination reaction. CH;CH,CH,CH,CCH3 Br b) For the major elimination product obtained in 5a), which stereoisomer (cis or trans) is obtained in greater yield? Draw the two isomers and provide the names of the compounds.For each reaction, decide whether substitution or elimination (or both) is possible, andpredict the products you expect. Label the major products. chlorocyclohexane + NaOCH3 in CH3OH4) Give the correct product with the correct stereochemistry. Me Me 5) Give the major product. hv HCI OC
- a Draw the structure of the intermediate (I) for the reaction below. Hg(O2CCH3)2 NaBH4 Product CH;OH H3C • Use the wedge/hash bond tools to indicate stereochemistry where it exists. If the reaction produces a racemic mixture, just drawv one stereoisomer.4) Eto ₂ 5) 2-Cyclohexene-1-one O₂Et + ethylace to acetate NaOEt NaOEtName the following compounds properly, including stereochemistry. CH3 H3C a) b) он Br e leom d Son lasal Br cle e en S) Draw the structures of the following compounds. a) acetonitrile Jud iyrdem snonet b) benzonitrile c) acetic acid d) formic acid outoge e) propyl propanoate y o trans Draw specific (no R's) examples of: the tet a) a hemiacetal b) a phosphorus ylide. c) an acid chloride d) a hydrate The reaction of acetone with NABH4 is a) a hydration b) a hydrolysis c) an oxidation d) a reduction pts) "Soap" may be defined as: a) a long chain carboxylic acid b) the sodium salt of a long chain acid c) the methyl ester of a long chain acid d) an anhydride of a long chain acid