The deuterium kinetic isotope effect for the halogenation of an alkane is defined in the following equation, where X: = Cl•or Br. deuterium kinetic rate of homolytic cleavage of a C–H bond by X• rate of homolytic cleavage of a C–D bond by X. isotope effect Predict whether chlorination or bromination would have a greater deuterium kinetic isotope effect.
The deuterium kinetic isotope effect for the halogenation of an alkane is defined in the following equation, where X: = Cl•or Br. deuterium kinetic rate of homolytic cleavage of a C–H bond by X• rate of homolytic cleavage of a C–D bond by X. isotope effect Predict whether chlorination or bromination would have a greater deuterium kinetic isotope effect.
Introduction to General, Organic and Biochemistry
11th Edition
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter11: Alkanes
Section: Chapter Questions
Problem 11.69P: Dodecane, C12H26, is an unbranched alkane Predict the following: Will it dissolve in water? Will it...
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The deuterium kinetic isotope effect for the halogenation of an
Predict whether chlorination or bromination would have a greater deuterium kinetic isotope effect.
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