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deuterium kinetic isotope effect rate of homolytic cleavage of a C-H bond by X.

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter24: Amines And Heterocycles

Section24.9: Heterocyclic Amines

Problem 21P

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Applications of Molecular Spectroscopy

When light sources pass through the diffraction grating then light splits into different wavelengths. The light source produces two types of patterns that are shown as destructive and non-destructive. The light source is in the form of quanta that is quantitation.

Question

The deuterium kinetic isotope effect for the halogenation of an alkane is defined in the following equation, where X. = Cl. or Br. Predict whether chlorination or bromination would have a greater deuterium kinetic isotope effect.

deuterium kinetic
isotope effect
rate of homolytic cleavage of a C-H bond by X.

Definition Definition Simplest organic compounds that contain only single bonds between carbon – carbon atoms and carbon – hydrogen bonds. This means they are a series of saturated compounds with a general molecular formula, C n H 2n+2 .

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