The dissociation vapor pressure of a salt A2B(s) A2ig) + B(g) at 367°C is 208 kPa but at 477°C it has risen to 547 kPa. For the dissociation reaction of A2B(5), calculate (i) the equilibrium constant, (ii) the standard reaction Gibbs energy, (iii) the standard enthalpy, and (iv) the standard entropy of dissociation, all at 422°C. Assume that the vapor behaves as a perfect gas and that A,H° and A,S° are independent of temperature in the range given.

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
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Chapter10: Effect Of Electrolytes On Chemical Equilibria
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The dissociation vapor pressure of a salt A2B(s) A2ig) + B(g) at 367°C is 208 kPa but at 477°C it has risen to
547 kPa. For the dissociation reaction of A2B(5), calculate (i) the equilibrium constant, (ii) the standard
reaction Gibbs energy, (iii) the standard enthalpy, and (iv) the standard entropy of dissociation, all at
422°C. Assume that the vapor behaves as a perfect gas and that A,H° and A,S° are independent of
temperature in the range given.
Transcribed Image Text:The dissociation vapor pressure of a salt A2B(s) A2ig) + B(g) at 367°C is 208 kPa but at 477°C it has risen to 547 kPa. For the dissociation reaction of A2B(5), calculate (i) the equilibrium constant, (ii) the standard reaction Gibbs energy, (iii) the standard enthalpy, and (iv) the standard entropy of dissociation, all at 422°C. Assume that the vapor behaves as a perfect gas and that A,H° and A,S° are independent of temperature in the range given.
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