The equilbirium constant for the isomerization reaction = trans 2-butene at selected temperatures are tabulated below. 883 T/K 826 779 733 702 686 K 1.10 1.20 1.36 1.49 1.63 1.72 Calculate the value of AH° and ASº at this temperature range. [-11.5 kJ mol·'; =-12.3 J K-' mol-l]
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- The relevant thermodynamic data, under standard conditions, for the reaction H2(g) + ½O2(g) → H2O(g) are summarised below: Entity: H2O(g) ∆hf ° kJ mol−1: −241.81 ∆gf ° kJ mol−1: −228.59 (a) Compute the equilibrium constant K of this reaction at T = 298 K. (b) Compute the corresponding K at 500 K. To simplify your calculations for this temperature, it is suggested you make the appropriate simplifying assumption. State the assumption you have made.10. What is ∆G for the decomposition of CaCO3 at 298K and a partial pressure of CO2 of 4*10-4 bar? ∆Gf0 for CaCO3(s), CaO(s) and CO2(g) are -1129 kJ/mol, -604 kJ/mol and -394 kJ/mol, respectively. CaCO3(s) → CaO(s) + CO2(g) A. 0 B. -131 kJ/mol C. 112 kJ/mol D. 131 kJ/mol E. 150 kJ/mol (Correct answer is C, I'm just looking for an explanation!).Heterogeneous chemical reactionConsider the following reaction to form an industrially important solid product B:A (g) ↔ B (s) + C (g) + D (g)a) How many phases are present?b) What is the maximum amount of solid product B you can make for each mole of A fed to the reactorif the reactor is operating at 400 ºC and 1 bar. Data: K = 10.43 at 400 ºC
- When nitric acid is produced industrially, nitrogen monoxide, NO, is first formed at high temperature. Bakefetr reacts NO on cooling further with oxygen to nitrogen dioxide: 2 NO(g) + O2 ⇌ 2 NO2 (g) Table 1: Thermodynamic data at 25°C. Bond ΔfHom Som Cop,m NO(g) 90.25 210.76 29.34 O2(g) 0.00 205.14 29.36 NO2(g) 33.18 240.06 37.20 1) Calculate (with all relevant intermediate calculations) the standard reaction Gibbs free energy, ΔrG25o, for reaction (1) at 25°C from the data in Table 1 2) Calculate (with all relevant intermediate calculations) the equilibrium constant K25, for reaction (1) at 25°C. 3) Industrially, however, the reaction does not proceed at 25°C but at 500°C. Therefore, calculate (with all relevant intermediate calculations) the standard reaction Gibbs free energy, ΔrG500o, for reaction (1) at 500°C under the assumption that the standard molar heat capacities, Cop, in Table 1 are independent of temperature in the interval [25°C, 500°C]Calculating Thermodynamic Values from an Equilibrium ConstantBackgroundAs discussed in lecture, the free energy for a reaction can be related to the equilibriumconstant through the formula below.K = e (-ΔG° / RT)Therefore if Kc for a reaction is known, Go can be determined, or vice versa. Furthermore, ifyou have the value for Go at two different temperatures, you can calculate H and S throughthe familiar equation for Gibbs energy below, since you have two unknowns but also twoequations.G = H – T SIn this lab you will be studying the solubility of borax (Na2B4O5(OH)4*8H2O), a slightly solublesodium salt, at two different temperatures. When solid borax is added to water, theequilibrium below is established.Na2B4O5(OH)4*8H2O (s) 2 Na+ (aq) + B4O5(OH)42- (aq) + 8 H2O(l)If you measure the concentrations for those substances that show up in the reaction quotient,then the Kc for the reaction at that temperature can be calculated. In this lab, theconcentration of borate ion…Thermodynamics Quantities for Selected Substances at 298.15 K (25⁰C) Substance ∆H⁰f (kJ/mol) ∆G⁰f (kJ/mol) S (J/K-mol) Carbon C2H2(g) 226.7 209.2 200.8 CO2(g) -393.5 -394.4 213.6 Hydrogen H2(g) 0 0 130.58 Oxygen O2(g) 0 0 205.0 H2O(l) -285.83 -237.13 69.91 What is the ∆S⁰ in the combustion of ethane in the presence of excess oxygen yields carbon dioxide and water: 2C2H2(g) + 7O2(g) → 4CO2(g) + 6H2O(l) in J/K?
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- In the gas phase reaction 2 A(g) + B(g) ⇋ 3 C (g) + 2 D (g), it was found that when 1.00 mol A, 2.00 mol B and 1.00 mol D were mixed and allowed to come to equilibrium at 25oC, the resulting mixture contained 0.9 mol C at a total pressure of 1.00 bar. Calculate the mole fractions of each species , Kx is , Kp is and isUnder equilibirum conditions at 565.3 K, [H2]=.06906 mol/L, [CO]=.01515 mol/L, [Ch3OH]= .0401 mol/L. What is value of Kc for this reaction at 565.3 K? (Data attached in picture)The molar solubility of rhombic sulfur (S(s, rhombic)) in water is very slight, only 1.9x10-8 mol/L. Compute for the dissolution of rhombic sulfur in water a. 44.1 kJ/mol b. 3.7 kJ/mol c. 19.1 kJ/mol d. -19.1 kJ/mol e. additional date is required