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The following chemical equations shows the stepwise formation constant expression K) of cach ox replaces two water. Fe + C2042 - [Fe(C204)] [Fe(C,O4) + C20, |Fe(C:O4)2] + C0 . ... [Fe(C204la) |Fe(ox), | (Fe(ox)"! K, (Fe"| lox| (Fefox),| K. K, |Fe(ox)"| [ox| [Fe(ox), |[ox) a) Write the overall formation constant experssion (Kr or Ba) demonstrating that the Ki is given by the product of the three stepwise constants. b) The value of successive stability constants decreases from KI to Ka. Why? c) The complex (Fe(C,O43) has high K value, which is about 2 x 1020, Give reason based on its structure.

The following chemical equations shows the stepwise formation constant expression K) of cach ox replaces two water. Fe + C2042 - [Fe(C204)] [Fe(C,O4) + C20, |Fe(C:O4)2] + C0 . ... [Fe(C204la) |Fe(ox), | (Fe(ox)"! K, (Fe"| lox| (Fefox),| K. K, |Fe(ox)"| [ox| [Fe(ox), |[ox) a) Write the overall formation constant experssion (Kr or Ba) demonstrating that the Ki is given by the product of the three stepwise constants. b) The value of successive stability constants decreases from KI to Ka. Why? c) The complex (Fe(C,O43) has high K value, which is about 2 x 1020, Give reason based on its structure.

General, Organic, and Biological Chemistry
General, Organic, and Biological Chemistry
7th Edition
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:H. Stephen Stoker
Chapter8: Solutions
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Problem 8.6EP: For each of the following pairs of solutions, select the solution for which solute solubility is...
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The following chemical equations shows the stepwise formation constant expression K) of cach ox replaces two water. Fel + C2042 [Fe(C,O4) + C20,2 - [Fe(C2O42) |Fe(C:04)2] + C0 - |Fe(C204)" |Fe(ox); | (Fe(ox)"! K, [Fe"| |ox| (Fe(ox),"| K = |Fe(ox)| |ox| [Fe(ox), |lox) a) Write the overall formation constant experssion (Kr or Ba) demonstrating that the Ki is given by the product of the three stepwise constants. b) The value of successive stability constants decreases from KI to Ka. Why? c) The complex (Fe(C,O43) has high Ki value, which is about 2 x 1020, Give reason based on its structure.
Transcribed Image Text:The following chemical equations shows the stepwise formation constant expression K) of cach ox replaces two water. Fel + C2042 [Fe(C,O4) + C20,2 - [Fe(C2O42) |Fe(C:04)2] + C0 - |Fe(C204)" |Fe(ox); | (Fe(ox)"! K, [Fe"| |ox| (Fe(ox),"| K = |Fe(ox)| |ox| [Fe(ox), |lox) a) Write the overall formation constant experssion (Kr or Ba) demonstrating that the Ki is given by the product of the three stepwise constants. b) The value of successive stability constants decreases from KI to Ka. Why? c) The complex (Fe(C,O43) has high Ki value, which is about 2 x 1020, Give reason based on its structure.
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