The following chemicals have been dissolved in the same amount of water: a) 1.5 mol of Fe(NO3)3(s); b) 2.1 mol of Cu(NO3)2(s); c) 6.0 mol of sucrose, C12H22011(s); d) 2.9 mol of NaCl(s). Circle all solutions below that will have the same new freezing point temperature. (Assume complete dissolution to ions for all ionic chemicals). Support your answer with the appropriate calculations. Solution a) b) c) d) C.

Consider two solutions, A and B, separated by an osmotic semipermeable membrane that allows only water to pass through, as shown in the diagram in Problem 8-113. Based on each of the following identities for solutions A and B, indicate whether the liquid level in compartment A, with time, will increase, decrease, or not change. a. A = 1.0 M glucose solution and B = 2.0 M glucose solution b. A = 5.0%(m/v) NaCl solution and B = 4.0%(m/v) NaCl solution c. A = 2.0 M Na2SO4 solution and B = 3.0 M KNO3 solution d. A = 2.0 M glucose solution and B = 1.0 M NaCl solution

Arrange the following aqueous solutions in order of decreasing freezing point. (The last three are all assumed to dissociate completely into ions in water.) (a) 0.20 m ethylene glycol (nonvolatile, nonelectrolyte) (b) 0.12 m K2SO4 (c) 0.10 m MgCl2 (d) 0.12 m KBr

Beaker A has 1.00 mol of chloroform, CHCl3, at 27C. Beaker B has 1.00 mol of carbon tetrachloride, CCl4, also at 27C. Equal masses of a nonvolatile, nonreactive solute are added to both beakers. In answering the questions below, the following data may be helpful. Write , =, or more information needed in the blanks provided. (a) Vapor pressure of solvent over beaker B vapor pressure of solvent over beaker A. (b) Boiling point of solution in beaker A boiling point of solution in beaker B. (c) Vapor pressure of pure CHCl3 vapor pressure of solvent over beaker A. (d) Vapor pressure lowering of solvent in beaker A vapor pressure lowering of solvent in beaker B. (e) Mole fraction of solute in beaker A mole fraction of solute in beaker B.

Some ethylene glycol, HOCH2CH2OH, is added to your cars cooling system along with 5.0 kg of water. If the freezing point of the water-glycol solution is 15.0 C, what mass of HOCH2CH2OH must have been added?