The following two sets of reactions [(a) and (b)] show possibilities for arrow pushing in individual reaction steps. Identify which is wrong and explain why. Then using arrow pushing correctly, label which molecule is the nucleophile and which is the electrophile. (b) (a) H-CI: . .- :O: :Ö: H3C H3C CH3 C=N C-CH3 + :CI: H3C CH3 H3C CH2 H3C H3C ":C=N: H-CI: H3C I+ C-CH3 + :C: H3C H3C CH3 CH3 C=N: C-CH2 H3C > H3C H3C C=N:
The following two sets of reactions [(a) and (b)] show possibilities for arrow pushing in individual reaction steps. Identify which is wrong and explain why. Then using arrow pushing correctly, label which molecule is the nucleophile and which is the electrophile. (b) (a) H-CI: . .- :O: :Ö: H3C H3C CH3 C=N C-CH3 + :CI: H3C CH3 H3C CH2 H3C H3C ":C=N: H-CI: H3C I+ C-CH3 + :C: H3C H3C CH3 CH3 C=N: C-CH2 H3C > H3C H3C C=N:
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter22: Reactions Of Benzene And Its Derivatives
Section: Chapter Questions
Problem 22.59P
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