Please help me answer part a and b with complete solution The gas-phase decomposition of di-tert-butylperoxide, (CH3)3 COOC(CH3)3, is first order inthe temperature range 110°C to 280°C with a first-order rate coefficientPart Ak = 3.2 x 1016 exp[-(164 kJ mol/RT] s=1.What is the value of AH# for this reaction in the temperaturerange between 110°Cand280°C?Express your answer with the appropriate units.kJΔΗ-molPart BWhat is the value of AS# for this reaction in the temperaturerange between 110°Cand280°C?Express your answer with the appropriate units.kJAS+mol • K

The gas-phase decomposition of di-tert-butyl peroxide, (CH3)3 COOC(CH3)3, is first order in the temperature range 110°C to 280°C with a first- order rate coefficient k = 3.2 x 1016 exp[-(164 kJ mol/RT] s-1.

The gas-phase decomposition of di-tert-butyl peroxide, (CH3)3 COOC(CH3)3, is first order in the temperature range 110°C to 280°C with a first- order rate coefficient k = 3.2 x 1016 exp[-(164 kJ mol/RT] s-1.

Chemistry: Principles and Reactions

8th Edition

ISBN:9781305079373

Author:William L. Masterton, Cecile N. Hurley

Publisher:William L. Masterton, Cecile N. Hurley

Chapter11: Rate Of Reaction

Section: Chapter Questions

Problem 39QAP: The decomposition of azomethane, (CH3)2N2, to nitrogen and ethane gases is a first-order reaction,...

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Question

Please help me answer part a and b with complete solution

The gas-phase decomposition of di-tert-butyl
peroxide, (CH3)3 COOC(CH3)3, is first order in
the temperature range 110°C to 280°C with a first-
order rate coefficient
Part A
k = 3.2 x 1016 exp[-(164 kJ mol/RT] s=1.
What is the value of AH# for this reaction in the temperature
range between 110°Cand
280°C?
Express your answer with the appropriate units.
kJ
ΔΗ-
mol
Part B
What is the value of AS# for this reaction in the temperature
range between 110°Cand
280°C?
Express your answer with the appropriate units.
kJ
AS+
mol • K

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