The iodide ion concentration in a solution may be determined by the precipitation of lead iodide. Pb2+ (aq) + 21 (aq) →→→→PbI₂(s) A student finds that 22.10 mL of 0.5530 M lead nitrate is needed to precipitate all of the iodide ion in a 25.00-mL sample of an unknown. What is the molarity of the iodide ion in the student's unknown? M

The iodide ion concentration in a solution may be determined by the precipitation of lead iodide. Pb2+ (aq) + 21 (aq) →→→→PbI₂(s) A student finds that 22.10 mL of 0.5530 M lead nitrate is needed to precipitate all of the iodide ion in a 25.00-mL sample of an unknown. What is the molarity of the iodide ion in the student's unknown? M

Introductory Chemistry: A Foundation

9th Edition

ISBN:9781337399425

Author:Steven S. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Donald J. DeCoste

Chapter15: Solutions

Section: Chapter Questions

Problem 63QAP

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A student is asked to identify the metal nitrate present in an aqueous solution. The cation in the solution can be either Na+, Ba2+, Ag+, or Ni2+. Results of solubility experiments are as follows: unknown + chloride ionsâ€”no precipitate unknown + carbonate ionsâ€”precipitate unknown + sulfate ionsâ€”precipitate What is the cation in the solution?
Separate samples of a solution of an unknown soluble ionic compound are treated with KCl, Na2SO4, and NaOH. A precipitate forms only when Na2SO4 is added. Which cations could be present in the unknown soluble ionic compound?
One method for determining the purity of aspirin (C9H8O4) is to hydrolyze it with NaOH solution and then to titrate the remaining NaOH. The reaction of aspirin with NaOH is as follows: A sample of aspirin with a mass of 1.427 g was boiled in 50.00 mL of 0.500 M NaOH. After the solution was cooled, it took 31.92 mL of 0.289 M HCl to titrate the excess NaOH. Calculate the purity of the aspirin. What indicator should be used for this titration? Why?
The cations Ba2+ and Sr2+ can be precipitated as very insoluble sulfates. (a) If you add sodium sulfate to a solution containing these metal cations, each with a concentration of 0.10 M, which is precipitated first, BaSO4 or SrSO4? (b) What will be the concentration of the first ion that precipitates (Ba2+ or Sr2+) when the second, more soluble salt begins to precipitate?
Relative solubilities of salts in liquid ammonia can differsignificantly from those in water. Thus, silver bromide issoluble in ammonia, but barium bromide is not (thereverse of the situation in water). Write a balanced equation for the reaction of anammonia solution of barium nitrate with an ammoniasolution of silver bromide. Silver nitrate is soluble inliquid ammonia. What volume of a 0.50 M solution of silver bromidewill react completely with 0.215 L of a 0.076 M solutionof barium nitrate in ammonia? What mass of barium bromide will precipitate fromthe reaction in part (b)?
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A 10.0-mL sample of potassium iodide solution was analyzed by adding an excess of silver nitrate solution to produce silver iodide crystals, which were filtered from the solution. KI(aq)+AgNO3(aq)KNO3(aq)+AgI(s) If 2.183 g of silver iodide was obtained, what was the molarity of the original KI solution?
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