The mechanism for the reaction described by the equation CH,NC(g) CH,CN(g) is suggested to be k1 (1) A(g) + M(g) = A° (g) + M(g) k-1 (2) A*(g) → B(g) where A(g) is CH,NC(g), M(g) is any gas molecule, A* (g) is CH, NC* (g) (an energized gas molecule), and B(g) is CH,CN(g). Assuming that [A*] is governed by steady-state conditions, derive the rate law for the production of CH, CN(g) in terms of [A], [M], and the appropriate k values.

Chemistry: Principles and Practice
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Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter13: Chemical Kinetics
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Problem 13.81QE: The gas-phase reaction of nitrogen monoxide with chlorine proceeds to form nitrosyl chloride....
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The mechanism for the reaction described by the equation
CH,NC(g)
CH, CN(g)
is suggested to be
k1
(1) A(g) + M(g) =
A" (g) + M(g)
k-1
k2
*
(2) А (g)
→ B(g)
where A(g) is CH, NC(g), M(g) is any gas molecule, A* (g) is CH,NC*(g) (an energized gas molecule), and B(g) is CH,CN(g).
Assuming that [A* ] is governed by steady-state conditions, derive the rate law for the production of CH, CN(g) in terms of [A],
[M], and the appropriate k values.
Transcribed Image Text:The mechanism for the reaction described by the equation CH,NC(g) CH, CN(g) is suggested to be k1 (1) A(g) + M(g) = A" (g) + M(g) k-1 k2 * (2) А (g) → B(g) where A(g) is CH, NC(g), M(g) is any gas molecule, A* (g) is CH,NC*(g) (an energized gas molecule), and B(g) is CH,CN(g). Assuming that [A* ] is governed by steady-state conditions, derive the rate law for the production of CH, CN(g) in terms of [A], [M], and the appropriate k values.
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