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The mechanism proposed for the oxidation of iodide ion, I, by the hypochlorite ion, CIO, in aqueous solution is shown 1. CIO (aq) + H,O(l) = HClO(aq) + OH-(aq) 2. I (aq) + HClO(aq) HIO(aq) + Cl(aq) 3. HIO(aq) + OH(aq) → IO (aq) + H₂O(l) Complete the rate law for the formation of IO implied by this mechanism. rate = k fast in both directions slow fast [CIO™] [HCIO] Answer Bank [H₂O] [IO™] [I] [HIO] [CI] [OH™]

The mechanism proposed for the oxidation of iodide ion, I, by the hypochlorite ion, CIO, in aqueous solution is shown 1. CIO (aq) + H,O(l) = HClO(aq) + OH-(aq) 2. I (aq) + HClO(aq) HIO(aq) + Cl(aq) 3. HIO(aq) + OH(aq) → IO (aq) + H₂O(l) Complete the rate law for the formation of IO implied by this mechanism. rate = k fast in both directions slow fast [CIO™] [HCIO] Answer Bank [H₂O] [IO™] [I] [HIO] [CI] [OH™]

Chemistry: The Molecular Science
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter3: Chemical Reactions
Section: Chapter Questions
Problem 125QRT: A student set up an experiment for six different trials of the reaction between 1.00-M aqueous...
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The mechanism proposed for the oxidation of iodide ion, I, by the hypochlorite ion, ClO¯, in aqueous solution is shown. fast in both directions 1. ClO (aq) + H₂O(1) ⇒ HC10(aq) + OH¯(aq) 2. I (aq) + HClO(aq) → HIO(aq) + Cl (aq) slow 3. HIO(aq) + OH¯(aq) → IO¯(aq) + H₂O(l) fast Complete the rate law for the formation of IO¯ implied by this mechanism. rate = k [C10¯] [HCIO] Answer Bank [H₂O] [IO] [I¯] [HIO] [CI] [OH-]
Transcribed Image Text:The mechanism proposed for the oxidation of iodide ion, I, by the hypochlorite ion, ClO¯, in aqueous solution is shown. fast in both directions 1. ClO (aq) + H₂O(1) ⇒ HC10(aq) + OH¯(aq) 2. I (aq) + HClO(aq) → HIO(aq) + Cl (aq) slow 3. HIO(aq) + OH¯(aq) → IO¯(aq) + H₂O(l) fast Complete the rate law for the formation of IO¯ implied by this mechanism. rate = k [C10¯] [HCIO] Answer Bank [H₂O] [IO] [I¯] [HIO] [CI] [OH-]
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