The pentacarbonyl metal, M(CO)5 complex, has two geometrical structures: trigonal bipyramidal or square pyramidal. Experimentally, it was found that the Ru(CO)5 complex show two stretching CO bands in the IR and three bands in the Raman region. According to these information, what would be the expected structure for Ru(CO)5?

Q: Explain reaction chemistry of CO with transition metals based on its Molecular orbital diagram?

A: Solution: Simply for any ligand to bind with transition metal required lone pair.  Let us know the…

Q: Give the systematic name for the following coordination compound: [NiCl₄]²⁻

A: [NiCl₄]²⁻ The above coordination compound systematic name is, Tetrachloronickelate (II) ion   A…

Q: For each complex, predict its structure, whether it is high spin or low spin, and the number of…

A: The complexes given are [Cu(NH3)4]2+ and [Ni(CN)4]2-.

Q: Question 3a and 3b

A: Products and balance of the equation will be:

Q: The molar mass of the coordination compound [M(NH3)4Cl2]Cl is 304.1 g/mol and the atomic mass of…

A:

Q: Write the electron configuration of chromium and explain the structure of the complex.

A:

Q: Give formulas for the following complex ions. tetracarbonyldihydroxochromium(III) ion

A: Given,  The formula of tetracarbonyldihydroxochromium(III) ion is:

Q: Write the state of hybridisation, the shape and the magnetic behaviour of the following complex…

A: (i) [Cr(NH3)4Cl2]Cl: Hybradisation of [Cr(NH3)4Cl2]Cl is d2sp3 Geometry of [Cr(NH3)4Cl2]Cl is…

Q: Does the [Ni(NH3)6]Cl2 and [Co(acac)3] complexes form optical isomers? if yes, what is the…

A: A complex is said to be an optical isomer when it exists also in the form of its mirror image which…

Q: Which of the following are high spin octahedral complex ions? (: [Cr(H2O)6]2* O (Mn(ox)3]4-…

A: When six ligands approach the metal ion, they arrange themselves in a geometry known as octahedral.…

Q: (a) Give two examples of coordination compounds used in industries.(b) Using valence bond theory,…

A: Since you have posted multiple questions, we will solve only one question for you. If you want the…

Q: Use your textbook or a chemical encyclopedia to describe the structure, shape, and bonding found in…

A: Co-ordination complex: In these types of complex ligands forms coordinate bonds with the metal atom…

Q: The compound PtCl>(en)2 is octahedral%; therefore we know that: A. The compound can have cis and…

A: Octahedral molecule means ,en is didentate ,and Cl is precipetated when Ag+ is added to form AgCl.…

Q: Give the systematic name for the following coordination compound: Na[Ag(CN)₂

A:

Q: How can I explain the complex trans - [CoBr2(en)2] by the crystalline field theory

A: This is an octahedral complex. The oxidation state of Co in this complex is +2. Co+2 = 1s2 2s2 2p6…

Q: Write the chemical formula for Tetraaquadibromochromium (III) chloride 2. What is the coordination…

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Q: structure of chelate when the polydentate ligand, ethylenediaminetetraacetate ion (EDTA 4 ) is…

A:

Q: For each metal complex, give the coordination number for the metal species. M(CO), F.]: Na…

A: The coordination number of a central atom in a molecule or crystal is the number of atoms, molecules…

Q: The crystal structure of [Cu(H2O)6]2+ displays axial bond lengths of 238 pm and equatorial bond…

A: The shape of transition metal complexes is determined by the tendancy of electron pairs to occupy…

Q: Draw the structure of the octahedral complex of iron thiocyanate, Fe(SCN)2(H2O)4

A: Four water groups are present at the square planar position while the thiocyanate group is present…

Q: Both [Ni(CN)4]X (where X represents counter cation) and [Ni(CO)4] complexes exhibit diamagnetic…

A:

Q: Plot the structure of the dinitro tetraammine cobalt (III) chloride complex compound and indicate…

A: Given, Complex compound is dinitro tetraammine cobalt(III) chloride, In this complex compound,…

Q: [Co(en)3][Cr(ox)3] and [Cr(en)3][Co(ox)3] are examples of_ а. ionization isomers b. linkage isomers…

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Q: In the solid state, [Fe(CO)5] possesses a trigonal bipyramidal structure. Predict the mass spectrum…

A: Fe(CO)5+→Fe(CO)4+ →Fe(CO)3+ →Fe(CO)2+ →Fe(CO)+ → Fe+ m/z=195       167              139…

Q: For each of the following molecules or polyatomic ions, draw the Lewis structure and indicate if it…

A: For each of the following molecules or polyatomic ions, draw the Lewis structure and indicate if it…

Q: Vanadium may have been used by some ancient animals ____________.

A: A number of species of marine algae produce vanadium bromoperoxidase as well as the closely related…

Q: Palladium(II) tends to form complexes with coordination number 4. A compound has the composition…

A: The chemical compounds consisting of neutral molecules or anions attached to the central metal atom…

Q: 1)Use the nature of the bonding in d-transition metal complexes with CO to explain why HCo(CO)4…

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Q: determine the electron count of an octahedral Ti^3+ complex. Calculate the crystal field splitting…

A: Crystal field splitting energy is defined as energy difference between two set of orbital t2g and eg

Q: Draw orbital-energy splitting diagrams and use the spectro-chemical series to show the orbital…

A: Spectrochemical series:- The arrangement of ligand in increasing order of their crystal field…

Q: Write the state of hybridization, the shape and the magnetic behaviour of the following complex…

A: In order to find out the hybridization following steps are followed: The oxidation state of metal is…

Q: What is the charge of the complex formed by a platinum(II) metal ion surrounded by two ammonia…

A: Given information: Complex is formed by a platinum(II) metal with two bromide ions and two ammonia…

Q: it is the coordination number of the central metal in [Cr(CO)6] ? Co ligand can be classified as:[ t…

A: Coordination chemistry is defined as branch of chemistry in which we study the bonding of metal with…

Q: percentage of mass of sulfur in the complex Ag (SCN)-2?

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Q: How many unpaired electrons are in the high-spin octahedral complex [Fe(NH3)6]3+?

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Q: What is the coordination number on the transition metal in the following compound? [Mn(H,O) ](NO3)2…

A: Answer

Q: PLEASE SKIP IF YOU HAVE ALREADY DONE THIS. Thank you

A: A coordination compound show linkage isomerism if it has ambient ligands. Ambient ligands are…

Q: Draw the geometrical isomers of complex [Pt(NH3)2Cl2]. (ii) On the basis of crystal field theory,…

A: Geometrical isomers: These are the two or more coordination compounds that contain the same number…

Q: Determine the oxidation state and coordination number of the metal ion in each complex ion. a.…

A: The oxidation state and coordination of the metal ion in each complex has to be given.

Q: Indicate the coordination number and the oxidation num ber of the metal for each of the following…

A: Since you have posted question with multiple sub-parts, we are entitled to answer the first 3 only.…

Q: Given the coordination compound Na4[Fe(ONO)2(ox)2]. - What is the type of hybridization of the…

A: Coordination Chemistry is branch of chemistry in which we deal with coordination compounds. In these…

Q: Consider the coordination compound [Cr(H,O),Cl]CI and calculate the the coordination number of the…

A: Coordination number: Coordination number of a metal ion in a complex can be define as the number of…

Q: Why Co+2 coordinate complexes are more stable than Fe+2 complexes?

A: A coordination complex is made up of a central atom or ion, which is typically metallic and is…

Atomic Structure

The basic structure of an atom is defined as the component-level of atomic structure of an atom. Precisely speaking an atom consists of three major subatomic particles which are protons, neutrons, and electrons. Many theories have been stated for explaining the structure of an atom.

Shape of the D Orbital

Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.