The reaction of methane with water to form carbon dioxide and hydrogen is non-spontaneous at 298 K. At what temperature will this system make the transition from non-spontaneous to spontaneous? The data refer to 298 K. CH:(g) + 2H2O(g) * CO2(g) + 4H2(g) Substance: CH4(g) H2O(g) CO:(g) H2(g) AH® {(kJ/mol): AG° f (kJ/mol): S°(J/K mol): -74.87 -241.8 -393.5 f ww -50.81 -228.6 -394.4 ww 186.1 188.8 213.7 130.7

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Chapter18: Thermodynamics And Equilibrium
Section: Chapter Questions
Problem 18.120QP
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The reaction of methane with water to form carbon dioxide and hydrogen is
non-spontaneous at 298 K. At what temperature will this system make the transition from
non-spontaneous to spontaneous? The data refer to 298 K.
CH4(g) + 2H2O(g) CO2(g)+ 4H2(g)
Substance:
CH(g)
H2O(g)
CO:(g)
H2(g)
AH® ¢ (kJ/mol):
AG° f (kJ/mol):
S°(J/K mol):
-74.87
-241.8
-393.5
ww
-50.81
-228.6
-394.4
www
186.1
188.8
213.7
130.7
Transcribed Image Text:The reaction of methane with water to form carbon dioxide and hydrogen is non-spontaneous at 298 K. At what temperature will this system make the transition from non-spontaneous to spontaneous? The data refer to 298 K. CH4(g) + 2H2O(g) CO2(g)+ 4H2(g) Substance: CH(g) H2O(g) CO:(g) H2(g) AH® ¢ (kJ/mol): AG° f (kJ/mol): S°(J/K mol): -74.87 -241.8 -393.5 ww -50.81 -228.6 -394.4 www 186.1 188.8 213.7 130.7
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