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- Propanamide and methyl acetate have about the same molar mass, both are quite soluble in water, and yet the boiling point of propanamide is 486 K, whereas that of methyl acetate is 330 K. Explain.Calculate the concentration of Y4-ion in 0.0100 M EDTA solution at pH 6. for pH 6, α4 = 2,2 x 10-5Assuming equal concentrations of conjugate base and acid, which one of the following mixtures is suitable for making a buffer solution with an optimum pH of 7.4–7.6? NaOCl / HOCl (K a = 3.2 × 10 –8) NH 3 / NH 4Cl (K a = 5.6 × 10 –10) NaNO 2 / HNO 2 (K a = 4.5 × 10 –4) NaCl / HCl CH 3COONa / CH 3COOH (K a = 1.8 × 10 –5)
- Calculate the pH of a mixture of 0.25 M acetic acid and 0.20 M sodium acetate. The pKa of acetic acid is 4.76.pH 3.5 4.5 5.5 6.5 7.5 8.5 Absorbance 0.098 0.027 0.068 0.028 0.032 0.054 Concentration in diluted supernatant (mg/ml) 0.196 0.054 0.136 0.0056 0.0064 0.0108 Concentration in undiluted supernatant (mg/ml) 0.98 0.27 0.68 0.28 0.32 0.54 Formula for the amount (g) of soluble proteins in the soy flour extract: In 15 ml of soy flour extract (with 1/50 dilution), Soluble protein (g) = (C x V x F) / 1000 C = concentration (mg/ml); F = dilution factor; V = volume of solution (ml) Calculate the % solubility of protein in the soy flour (Assume the soy flour contains 35% protein (w/w))pH 3.5 4.5 5.5 6.5 7.5 8.5 Absorbance 0.098 0.027 0.068 0.028 0.032 0.054 Concentration in diluted supernatant (mg/ml) 0.196 0.054 0.136 0.0056 0.0064 0.0108 Concentration in undiluted supernatant (mg/ml) 0.98 0.27 0.68 0.28 0.32 0.54 Formula for the amount (g) of soluble proteins in the soy flour extract: In 15 ml of soy flour extract (with 1/50 dilution), Soluble protein (g) = (C x V x F) / 1000 C = concentration (mg/ml); F = dilution factor; V = volume of solution (ml) Calculate the amount of soluble protein (in grams) in the soy flour extract
- Consider a buffer solution that contains 0.55 M NH2CH2CO2H and 0.35 M NH2CH2CO2Na. pKa(NH2CH2CO2H)=9.88. a. Calculate its pH. b. Calculate the change in pH if 0.155 g of solid NaOH is added to 250 mL of this solution. c. If the acceptable buffer range of the solution is ±0.10 pH units, calculate how many moles of H3O+ can be neutralized by 250 mL of the initial buffer.How many grams of NaCl are required to prepare 100 mL of a solution of 1 M NaCl? (NaCl molecular weight = 58.44 g/mol)At 39.9ºC, a solution of ethanol (XetOH = 0.9006, P * etOH = 130.4 Torr) and isooctane (P * iso = 43.9 Torr) forms a vapor phase with YetOH = 0.6667. The total pressure is 185.9 a. Calculate the activity and the activity coefficient of each component.b. Calculate the total pressure the solution would have if it were ideal.c. Comparing the ideal pressure to the actual pressure, what does this indicate about the molecular interactions?
- How many grams of glucose (C6H2O6 molecular mass =180daltons) would be present in one liter of a 1M (molar) solution of glucose?For ferrocene (C10H10Fe) the enthalpy of sublimation is 73.2 kJ/mol and the entropy of sublimation is 243 J/mol.K. What is the sublimation temperature of ferrocene in degrees Celsius?Describe the preparation of the following solutions include all mathematic calculations and equipment of the laboratory needed A.500 mm of a solution of KNO 1.50 M B. 150 g of a solution 5.0% of NaC2H3O2 C. 500 mm of a solution of NaOH 0.50 M from a solution of NaOH 6.0 M