The solubility of silver chloride increases in the presence of aqueous ammonia, NH3(aq), due to the formation of the complex ion as represented by the following equilibrium: AgCl(s) + 2 NH3(aq) → Ag(NH3)2*(aq) + Cl'(aq) The Kf for the complex ion Ag(NH3)2* is 1.7 x 107. The Ksp for AgCl is 1.8 x 10 10. The molar solubility of AgCl in 6.0 M NH3 is...

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Chapter17: Spontaneity, Entropy, And Free Energy
Section: Chapter Questions
Problem 123CP: Sodium chloride is added to water (at 25C) until it is saturated. Calculate the Cl concentration in...
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The solubility of silver chloride increases in the presence
of aqueous ammonia, NH3(aq),
due to the formation of the complex ion as represented by
the following equilibrium:
AgCI(s) + 2 NH3(aq) Ag(NH3)2*(aq) + Cl(aq)
The Kf for the complex ion Ag(NH3)2* is 1.7 x 107. The Kgp
for AgCl is 1.8 x 10-10.
The molar solubility of AgCl in 6.0 M NH3 is...
Transcribed Image Text:The solubility of silver chloride increases in the presence of aqueous ammonia, NH3(aq), due to the formation of the complex ion as represented by the following equilibrium: AgCI(s) + 2 NH3(aq) Ag(NH3)2*(aq) + Cl(aq) The Kf for the complex ion Ag(NH3)2* is 1.7 x 107. The Kgp for AgCl is 1.8 x 10-10. The molar solubility of AgCl in 6.0 M NH3 is...
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