The sulfur from 4.00g steel is evolved as dihydrogen sulfide gas and titrated with 1.60 mL of 0.050ON iodine solution. What is the percentage of sulfur in the steel? H2S + 12 → S + 2l- + 2H+ AsO33- + 2HCO3- + l2 → AsO43- + 21- + 2CO2 + H2O 2Cu2+ + 41- → 2Cul + l2 103 + 61- + 6H+ → 3l2 + - 3H2O - 312 + - 3H2O
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- Given: You weigh out exactly 0.200 g of Fe(NH4)2(SO4)2·6H2O and dissolve it in the 100.00 mL volumetric flask. You then pipette 2.00 mL of this solution into the 50.00 mL volumetric flask to prepare the stock standard tris-bipyridyl-iron(II) solution. a. Calculate the molar concentration of iron(II) in this solution in the 50.00 mL volumetric flask. (The MW of Fe(NH4)2(SO4)2·6H2O is 392.14 g/mol) (answer a given the information above)An exhausted zeolite softener was regenerated by passing 100 litres, of NaCl. Solution containing 150 gm per lit. of NaCl. How many lit. of a sample of H2O of hardness 300 ppm can be softened by this softener? (Given at wts. for C = 12, O = 16, Na = 23, CI = 35.5, Ca = 40).Pyrolusite (MnO2) is dissolved in hydrochloric acid:MnO2 + HCl → MnCl2 + H2O + Cl2The chloride was passed into potassium iodide solution where it liberated iodine:Cl2 + KI → KCl + I2The iodine liberated was estimated by adding sodium thiosulfate, the reaction beingI2 + Na2S2O3 → NaI + Na2S4O6If 5.6 g of crystallized sodium thiosulfate, Na2S2O3 5H2O ,were used up, how many grams of manganese were present?MW (g/mole): I =126.9; Mn =54.94; Cl = 35.45; K = 39.09; Na = 23; S = 32
- Calculate the time, in minutes, needed to plate 17.697 g of metal M at 43 Amps. The molar mass of metal M is 57.915 g/mol. M6+ + 6 e– → M Recall that, C = A*s, and Faraday’s constant, F, is 96,485 C/mole of electrons.A sample is known to consists of NaOH, or NaHCO3 or Na2CO3 or possible compatible mixture of these, together with inert matter. With methyl orange, a 1.100 g sample requires 31.4 ml of HCl ( 1.000ml is equivalent to 0.0140 g CaO). With phenolphthalein , the same weight of the sample requires 13.3 ml of the acid. Calculate the percent inert matter in the sample? ( ans. 17.7%)The chief chemist of the Brite-Metal Electroplating Co. isrequired to certify that the rinse solutions that are discharged from the company’s tin-plating process into the municipal sewer system contain no more than 10 ppm (parts per million) by mass of Sn2+. The chemist devises the following analytical procedure to determine the concentration. At regular intervals, a 100-mL (100-g) sample is withdrawn from the waste stream and acidified to pH = 1.0. A starch solution and 10 mL of 0.10 M potassium iodide are added, and a 25.0-mA current is passed through the solution between platinum electrodes. Iodine appears as a product of electrolysis at the anode when the oxidation of Sn2+ to Sn4+ is practically complete and signals its presence with the deep blue color of a complex formed with starch. What is the maximum duration of electrolysis to the appearance of the blue color that ensures that the concentration of Sn2+does not exceed 10 ppm?
- A 0.2653 g of pure potassium dichromate was dissolved in 15 mL of 1.5 M sulfuric acid and transferred to a 250.0 mL volumetric flask and diluted to the mark with distilled water. A 25.0 mL aliquot of this solution was transferred to another 250.0 mL volumetric flask and diluted to the mark with distilled water and this solution has an absorbance 0f 0.387 in a 2.00 cm cell. Calculate the molar absorptivity of potassium dichromate.A 1.000 g sample containing chlorides, iodides and inert materials was treated with dilute nitric acid followed by AgNO3. A precipitate of AgCl (143.32) and AgI (234.77) was produced and weighs 0.9238 g. On heating in a current of Cl2, the AgI is converted to AgCl, and the resulting product weighs 0.7238 g. Find the percentage of a) NaI (149.89) and b) NaCl (58.44) in the sampleA (3.6500 g) of impure ammonium aluminium sulfate (NH4Al(SO4)2)) was treated with ammonia (NH3(aq)) producing hydrous alumina Al2O3.xH2O. The collected precipitate was filtered, washed, and ignited at 1000 °C to give 0.4935 g Al2O3 (Mw 101.9635 g/mol). Determine: a. % Al2O3 b. %Al c. Express concentration of Al in ppm.
- A sample of an iron ore was prepared for Fe3+ analysis as following: 3.4g of the sample was added anddissolved in acid environment then diluted to 250 mL using volumetric flask. After that, 10 mL of the resultingsolution was transferred by pipet to a 50-mL volumetric flask and continue to be diluted. The scientists foundout that this solution gives the concentration of Fe3+ as 2.3 mg/L. Find the weight percentage of Fe3+ in theoriginal sample.In a beaker 20mL of 0.5M Ca(OH)2 and 80mL of 0.5M CH3COOH are mixed and then this mixture is added on 2g of active coal. After waiting for about 20 minutes the solution is filtered and the filter is titrated by 1M NaOH solution in the presence of an indicator. 10mL of the NaOH solution has been used. Calculate the amount of acetic acid adsorbed per gram of the coal in moles. Explain all the steps and reactions of the experimental process by your own comments.35.A sample of pyrolusite weighs 0.5000 g. To this is added 0.6674 g of As2O3 and dilute acid. After solvent action has ceased, the excess three-valent arsenic is titrated with 45.00 mL of 0.1000 N KMnO4. Calculate the oxidizing power of the pyrolusite in terms of percemtage MnO2. 36. A solution of Iodinebia such concentration that 20.0 mL are required to titrate the antimony in a 0.100 g sample containing 84.93% Sb2S3(339.7 g/mol). What is the value of 1.00 mL of this Iodine in terms of grams sulfue in tiration?