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The table of "Axial Strain Energies for Monosubstituted Cyclohexanes" found in the "Strain Energy Increments" section of the Reference tool is useful for answering this question. CH=CH₂ C a cl Group a is Group b is Group c is H b C C

The table of "Axial Strain Energies for Monosubstituted Cyclohexanes" found in the "Strain Energy Increments" section of the Reference tool is useful for answering this question. CH=CH₂ C a cl Group a is Group b is Group c is H b C C

Organic Chemistry
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter2: Alkanes And Cycloalkanes
Section: Chapter Questions
Problem 2.46P
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Ing and learning re... Substituent(solvent) -CH3 -CH₂CH3 -CH(CH3)2 -C(CH3)3 phenyl cyclohexyl -CH=CH₂ -CCH, ethynyl -CHO -COCH3 -CO₂H -CO,CH,CH3 -C1 -Br -CN, cyano -OH (cyclohexane) -OH (isopropanol) -OCH3 -NH₂ (toluene) -NH2(CH3OCH,CH,OH/H,O) -NO₂ 5.1 5.9 5.0 2.5 2.5 0.8 2.5 4.0 2.5 5.2 7.1 4.8 Appli...lication Form Strain Energy Increments kJ/mol 7.3 1.7 7.5 1.8 9.2 2.2 20 4.8 11.7 2.8 9.2 2.2 6.2 1.5 2.1 0.5 3.0 0.7 1.2 1.4 1.2 0.6 0.6 0.2 0.6 1.0 0.6 1.2 1.7 11 EMT Certification kcal/mol CUA Use Strain Energy I
Transcribed Image Text:Ing and learning re... Substituent(solvent) -CH3 -CH₂CH3 -CH(CH3)2 -C(CH3)3 phenyl cyclohexyl -CH=CH₂ -CCH, ethynyl -CHO -COCH3 -CO₂H -CO,CH,CH3 -C1 -Br -CN, cyano -OH (cyclohexane) -OH (isopropanol) -OCH3 -NH₂ (toluene) -NH2(CH3OCH,CH,OH/H,O) -NO₂ 5.1 5.9 5.0 2.5 2.5 0.8 2.5 4.0 2.5 5.2 7.1 4.8 Appli...lication Form Strain Energy Increments kJ/mol 7.3 1.7 7.5 1.8 9.2 2.2 20 4.8 11.7 2.8 9.2 2.2 6.2 1.5 2.1 0.5 3.0 0.7 1.2 1.4 1.2 0.6 0.6 0.2 0.6 1.0 0.6 1.2 1.7 11 EMT Certification kcal/mol CUA Use Strain Energy I
Cyclohexane derivatives exist primarily in the most stable of the available chair conformations. Give the position, axial or equatorial, of each of the three groups shown when the ring is in the most stable chair conformation. If a group divides its time equally between axial and equatorial positions, indicate this with ax/eq. The table of "Axial Strain Energies for Monosubstituted Cyclohexanes" found in the "Strain Energy Increments" section of the Reference tool is useful for answering this question. CH=CH₂ с H a ci Group a is Group b is Group c is b Ⓒ C C
Transcribed Image Text:Cyclohexane derivatives exist primarily in the most stable of the available chair conformations. Give the position, axial or equatorial, of each of the three groups shown when the ring is in the most stable chair conformation. If a group divides its time equally between axial and equatorial positions, indicate this with ax/eq. The table of "Axial Strain Energies for Monosubstituted Cyclohexanes" found in the "Strain Energy Increments" section of the Reference tool is useful for answering this question. CH=CH₂ с H a ci Group a is Group b is Group c is b Ⓒ C C
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