This is an example of a [1,3] sigmatropic rearrangement. Can someone explain how this is 1,3 (number the carbons) and draw the anion / cation transition state

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter18: Nuclear Reactions
Section: Chapter Questions
Problem 81QAP
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This is an example of a [1,3] sigmatropic rearrangement. Can someone explain how this is 1,3 (number the carbons) and draw the anion / cation transition state

 

AcO,
OAC
.D
D
-OAc
H-
OAc
DH
H
H
4-electron
Möbius
Transcribed Image Text:AcO, OAC .D D -OAc H- OAc DH H H 4-electron Möbius
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