Titration of a Weak Acid Report Sheet Molarity of NAOH used: 0.100 M Part A. Show calculations for 1 trial: moles of acd = 0.100M X %3D Trial 1 Trial 2 Trial 3 Average 18mL 18.75m 18SC3ML mL OH added at 19ML equivalence point Molarity

Chemistry: An Atoms First Approach
2nd Edition
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Steven S. Zumdahl, Susan A. Zumdahl
Chapter14: Acid- Base Equilibria
Section: Chapter Questions
Problem 118CP: Malonic acid (HO2CCH2CO2H) is a diprotic acid. In the titration of malonic acid w ith NaOH,...
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Titration of a Weak Acid
Report Sheet
Molarity of NaOH used:
0.100 M
Part A. Show calculations for 1 trial:
Moles of acd = 0.100M X
%3D
Trial 1
Trial 2
Trial 3
Average
18ml
18.75ML 18.ST3ML
mL OH added at
19ML
equivalence point
Molarity
Transcribed Image Text:Titration of a Weak Acid Report Sheet Molarity of NaOH used: 0.100 M Part A. Show calculations for 1 trial: Moles of acd = 0.100M X %3D Trial 1 Trial 2 Trial 3 Average 18ml 18.75ML 18.ST3ML mL OH added at 19ML equivalence point Molarity
Titration of a Weak Acid
Strong Acid & Strong Base
14
Read section 16.4 of the textbook before doing this experiment. This section will help you
answer the prelab questions as well as understand the experiment.
12
Weak Acid & Strong Base
14-
10
Equivalence point
8-
12-
Before oquivalence point
10-
Objectives:
After equivalence point
(OH in excess)
(buffer range)
6.
6-
Determine the concentration of a weak acid solution by titration.
O Determine the molar mass of a weak acid from titratian data.
Determine the pKa of a weak acid from titration data.
4.
Equivalence point
(weak conjugate base)
4-
2-
Initial pH (wenk acid)-
0-
0-
10
80
25
50
Volume of NaOH added (mL)
Volume of NaOH added (ml)
Background:
A neutralization reaction occurs when and acid and base are mixed. Titration is a method to
determine the concentration of an acid or base by following these general steps:
Experiment: Titration of a weak acid with a strong base
The following neutralization reaction occurs when a weak acid and base are mixed:
1) a specified volume of acid (or base) of unknown concentration is added to a beaker
2) a pH electrode is placed into the beaker and the solution is mixed
3) base (or acid) of known concentration is added to the beaker in fixed volumes (one or
two mL) and the pH is recorded
4) the volume of base (or acid) of known concentration added to the beaker required to
reach the equivalence point is used to calculate the moles of base (or acid) added
5) using stoichiometry, the number of moles of unknown acid (or base) present in the flask
is calculated
6) the molarity of the unknown acid (or base) is calculated from the volume of the acid (or
base) added to the beaker.
7) the pKa is calculated by finding the volume halfway to the equivalence point. Follow
over to the pH at this volume and this is the pka.
HA + OH → H,0 +A-
HA represents a weak acid and A is its conjugate base.
At the equivalence (or stoichiometric) point mols OH = mols HA
Since you know the volume and molarity of added hydroxide, you also know the number of
moles of hydroxide. Using the stoichiometry, which is 1:1 in this case, the number of moles of
acid will be the same value. Finally, the molarity of the acid can be calculated, taking into
account the calculated value of moles and the volume of acid used.
A plot of pH vs. added volume of base, is a titration curve and it will have the shape shown
Part A: Liquid Weak Acid
Procedure:
1. You will do three trials of the titration of a weak acid. Pipet 25 ml of unknown acid into a
14
250 mL beaker and add 50 ml of deionized water using a graduated cylinder. Prepare a total
of three beakers with this mixture.
-equivalence
point
2. Prepare a buret by filling it with a standardized NaOH solution of known molarity. Be sure to
record the molarity in your notebook.
3. Place one of the beakers on the stir plate, add a stir bar and begin stirring.
pKa
4 Vease Vpase
4. Remove the pH electrode from the storage solution and rinse with deionized water.
5. Calibrate the electrode according to the instructions for the MicroLab unit.
6. Insert the electrode into the beaker taking care not to hit the bottom or sides of the beaker.
Examples of titration curves for strong and weak acids are shown below. Note the differences in
shape and the pH at the equivalence point:
7. Record the initial pH.
8 mL
10 mL
12ML
4.17
3.98
4.19
4.38
6 mL
8mL
l0mL
12ML 4.59
14ML 4.92
5.14
8. Add NaOH from the buret in "1 or 2 ml aliquots and record pH after each addition. Keep a
running total of NaOH added when using the MicroLab unit.
4.36
As
the titration approaches the equivalence point, the pH will begin to change rapidly so
4.57
9.
add the NaOH slowly (drop-wise) at this point.
14ML
16mL
4.79
10. Continue to the titration until a pH of ~12 is reached.
11. Repeat the analysis with the other two beakers.
5.09
18ML
16ML
5.14
10.26 >8.0PH
11.15
24 mL l1.41
Calculations
Plot all three titration curves on one graph using Excel.
Volume of NaOH added in ml on the x-axis and pH on the y-axis
20 mL
18 mL 5.966
22 mL
9.4!
10. 0e
19.5mL
Determine the molarity the unknown acid for each trial.
1. Calculate mols of OH added at the equivalence point.
2. Calculate mols of acid present.
3. Taking into account the volume of acid used, calculate the molarity.
20 mL 10.5o
22ML 11.20
24mL il.43
26 mL 11.54
28 mL l1.62
26ML 11.53
28 mL 11.62
Calculate the average molarity.
Initial
3.05
Trial 3
2ml 3.49
4mL 3.11
omL 4.05
8ML 4.23
10 mL 4.42
12ML 4.62
he a
Part B: Solid Weak Acid
19.15 mL 10.42
20.00ML 10.G0
22.00 ML I1.23
24.00ML l1.43
26.00ML l1.55
28.00mL Il.633
o Jolg A
it the
acid
Procedure:
1. Dissolve 0.5 g of an unknown weak acid in
80 mL of deionized water.
OH- a
2.
2. Add 25 ml of the dissolved acid using a volumetric pipet into a 250 mL beaker.
mass
3. Titrate the acid as in Part A.
ddec
curve
14ML 4.85
I6ML 520
1 8mL 6.02
18.25 mL 6.40
4. Repeat the titration two more times.
Calculations
Plot all three titration curves on one graph using Excel.
Volume of NaOH added in mL on the x-axis and pH on the y-axis
molarity of NAOH :0.100 M
18.50ML 7.68
18.75 mL 9.1> 8.0PH.
19.00 ML 9.54
19.25mL 9.92
19.50 ML 10.2I
T1
T2
T3
PH Buffer
Determine the molar mass of the unknown acid.
4.07
7.00
1. Calculate mols of OH added at the equivalence point in each trial.
2. Calculate mols of acid present in each trial.
3. Calculate mols of acid present in all three trials combined
4. Taking into account the mass of acid used, calculate the molar mass in the units g/mol.
10.01
Volume
PH
Initial PH:
28ML 28ML
28ML
11.62
I1.62
11.63
Calculate the pka of the acid for each trial, and the average pKa for all trials.
296
297
3.05
Hd
Transcribed Image Text:Titration of a Weak Acid Strong Acid & Strong Base 14 Read section 16.4 of the textbook before doing this experiment. This section will help you answer the prelab questions as well as understand the experiment. 12 Weak Acid & Strong Base 14- 10 Equivalence point 8- 12- Before oquivalence point 10- Objectives: After equivalence point (OH in excess) (buffer range) 6. 6- Determine the concentration of a weak acid solution by titration. O Determine the molar mass of a weak acid from titratian data. Determine the pKa of a weak acid from titration data. 4. Equivalence point (weak conjugate base) 4- 2- Initial pH (wenk acid)- 0- 0- 10 80 25 50 Volume of NaOH added (mL) Volume of NaOH added (ml) Background: A neutralization reaction occurs when and acid and base are mixed. Titration is a method to determine the concentration of an acid or base by following these general steps: Experiment: Titration of a weak acid with a strong base The following neutralization reaction occurs when a weak acid and base are mixed: 1) a specified volume of acid (or base) of unknown concentration is added to a beaker 2) a pH electrode is placed into the beaker and the solution is mixed 3) base (or acid) of known concentration is added to the beaker in fixed volumes (one or two mL) and the pH is recorded 4) the volume of base (or acid) of known concentration added to the beaker required to reach the equivalence point is used to calculate the moles of base (or acid) added 5) using stoichiometry, the number of moles of unknown acid (or base) present in the flask is calculated 6) the molarity of the unknown acid (or base) is calculated from the volume of the acid (or base) added to the beaker. 7) the pKa is calculated by finding the volume halfway to the equivalence point. Follow over to the pH at this volume and this is the pka. HA + OH → H,0 +A- HA represents a weak acid and A is its conjugate base. At the equivalence (or stoichiometric) point mols OH = mols HA Since you know the volume and molarity of added hydroxide, you also know the number of moles of hydroxide. Using the stoichiometry, which is 1:1 in this case, the number of moles of acid will be the same value. Finally, the molarity of the acid can be calculated, taking into account the calculated value of moles and the volume of acid used. A plot of pH vs. added volume of base, is a titration curve and it will have the shape shown Part A: Liquid Weak Acid Procedure: 1. You will do three trials of the titration of a weak acid. Pipet 25 ml of unknown acid into a 14 250 mL beaker and add 50 ml of deionized water using a graduated cylinder. Prepare a total of three beakers with this mixture. -equivalence point 2. Prepare a buret by filling it with a standardized NaOH solution of known molarity. Be sure to record the molarity in your notebook. 3. Place one of the beakers on the stir plate, add a stir bar and begin stirring. pKa 4 Vease Vpase 4. Remove the pH electrode from the storage solution and rinse with deionized water. 5. Calibrate the electrode according to the instructions for the MicroLab unit. 6. Insert the electrode into the beaker taking care not to hit the bottom or sides of the beaker. Examples of titration curves for strong and weak acids are shown below. Note the differences in shape and the pH at the equivalence point: 7. Record the initial pH. 8 mL 10 mL 12ML 4.17 3.98 4.19 4.38 6 mL 8mL l0mL 12ML 4.59 14ML 4.92 5.14 8. Add NaOH from the buret in "1 or 2 ml aliquots and record pH after each addition. Keep a running total of NaOH added when using the MicroLab unit. 4.36 As the titration approaches the equivalence point, the pH will begin to change rapidly so 4.57 9. add the NaOH slowly (drop-wise) at this point. 14ML 16mL 4.79 10. Continue to the titration until a pH of ~12 is reached. 11. Repeat the analysis with the other two beakers. 5.09 18ML 16ML 5.14 10.26 >8.0PH 11.15 24 mL l1.41 Calculations Plot all three titration curves on one graph using Excel. Volume of NaOH added in ml on the x-axis and pH on the y-axis 20 mL 18 mL 5.966 22 mL 9.4! 10. 0e 19.5mL Determine the molarity the unknown acid for each trial. 1. Calculate mols of OH added at the equivalence point. 2. Calculate mols of acid present. 3. Taking into account the volume of acid used, calculate the molarity. 20 mL 10.5o 22ML 11.20 24mL il.43 26 mL 11.54 28 mL l1.62 26ML 11.53 28 mL 11.62 Calculate the average molarity. Initial 3.05 Trial 3 2ml 3.49 4mL 3.11 omL 4.05 8ML 4.23 10 mL 4.42 12ML 4.62 he a Part B: Solid Weak Acid 19.15 mL 10.42 20.00ML 10.G0 22.00 ML I1.23 24.00ML l1.43 26.00ML l1.55 28.00mL Il.633 o Jolg A it the acid Procedure: 1. Dissolve 0.5 g of an unknown weak acid in 80 mL of deionized water. OH- a 2. 2. Add 25 ml of the dissolved acid using a volumetric pipet into a 250 mL beaker. mass 3. Titrate the acid as in Part A. ddec curve 14ML 4.85 I6ML 520 1 8mL 6.02 18.25 mL 6.40 4. Repeat the titration two more times. Calculations Plot all three titration curves on one graph using Excel. Volume of NaOH added in mL on the x-axis and pH on the y-axis molarity of NAOH :0.100 M 18.50ML 7.68 18.75 mL 9.1> 8.0PH. 19.00 ML 9.54 19.25mL 9.92 19.50 ML 10.2I T1 T2 T3 PH Buffer Determine the molar mass of the unknown acid. 4.07 7.00 1. Calculate mols of OH added at the equivalence point in each trial. 2. Calculate mols of acid present in each trial. 3. Calculate mols of acid present in all three trials combined 4. Taking into account the mass of acid used, calculate the molar mass in the units g/mol. 10.01 Volume PH Initial PH: 28ML 28ML 28ML 11.62 I1.62 11.63 Calculate the pka of the acid for each trial, and the average pKa for all trials. 296 297 3.05 Hd
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