Titration of Ca2+ and Mg2+ in a 50.00-mL sample of hard water required 23.65 mL of 0.01205 M EDTA. A second 50.00-mL aliquot was made strongly basic with NaOH to precipitate Mg2+ as Mg(OH)2(s). The supernatant liquid was titrated with 14.53 mL of the EDTA. Calculate the concentration in ppm of CaCO3 in the sample. Calculate the concentration in ppm of MgCO3 in the sample.

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter17: Complexation And Precipitation Reactions And Titrations
Section: Chapter Questions
Problem 17.35QAP
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  1. Titration of Ca2+ and Mg2+ in a 50.00-mL sample of hard water required 23.65 mL of 0.01205 M EDTA. A second 50.00-mL aliquot was made strongly basic with NaOH to precipitate Mg2+ as Mg(OH)2(s). The supernatant liquid was titrated with 14.53 mL of the EDTA.
    1. Calculate the concentration in ppm of CaCO3 in the sample.
    2. Calculate the concentration in ppm of MgCO3 in the sample.
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