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- Calculate the saturation indices of the solutions describe below and classify each as undersaturated, supersaturated, or in equilibrium. Saturation state with respect to: Anhydrite (CaSO4) [Ca2+] = 0.00002 mM [SO42-] = 25 mM “Amakinite” (Fe(OH)2) [Fe2+] = 0.1 mM; [OH-] = 0.0001 mM Siderite (FeCO3) [Fe2+] = 3 mM; [CO32-] = 10 mMGiven the solubility of ferrihydrite (Fe(OH)3) and goethite (FeOOH), with dissolution reactions shown below: [1] Fe(OH)3 3 H+ à Fe3+ + 3 H2O Ksp = 8.4 x 10^4 ∆ Gr0 = -28 KJ/mol Solubility of Fe(OH3) = 7.468 [2] FeOOH + 3 H+ à Fe3+ + 2 H2O Ksp = 8.8 x 10^-2 ∆ Gr0 = 6 KJ/mol Solubility of FeOOH = 0.353 QUESTION: [A] How much Fe3+ from ferrihydrite would dissolve at pH 2 ? [B] How much Fe3+ from ferrihydrite would dissolve at pH 7 ? [C] How much Fe3+ from goethite would dissolve at pH 2 ? [D] How much Fe3+ from goethite would dissolve at pH 7 ?Would you expect calcite to be appreciably soluble in a solution whose pH is maintained at 4? A solution at pH? A solution containing 0.1 m H2S? where might you find such solutions in nature?
- what wt. of limestone containing 9.57% Mg must be taken for analysis in order to precipitate of 0.551g Mg2P2O7? how many grams of Na2SO4 are required to ppte Ag2SO4 from 2.000t of AgNO3? a sample of magnetite (impure Fe3O4) weighing 0.5000g is fused with oxidizing flux and the ferric compound formed is eventually precipitated as ferric hydroxide and ignited to ferric oxide which weighs 0.4980calculate %Fe & %Fe2O31. What are the practical implications of alloying in carbon and alloy steels? 2. Make use of drawings of segments of the Fe-Cr phase diagram to illustrate the reason for the existence offerritic, martensitic and austenitic stainless steels by also noting the influence of specific alloying elementswhere-applicable. .A 0.9352g sample of ore containing Fe³+, Al³+ and Sr²+ was dissolved and made up to 500.00 mL. The analysis of metals was performed using complexation volumetry. Initially, an aliquot of 50.00 mL had its pH adjusted to 1.0 and titrated with a standard 0.03145 mol/L EDTA solution, requiring 6.95 mL to reach the end point. Subsequently, another 25.00 mL aliquot was buffered at pH=5 and titrated with the same EDTA solution, requiring 6.24 mL to reach the end point. Finally, a third aliquot of 25.00 mL was titrated at pH=11, requiring 11.10 mL of the same EDTA solution to complete the titration. Given the molar masses: Fe=55.845 g/mol; Al-26.982 g/mol and Sr-87.620 g/mol. a) Determine the percentage of each of the metals in the sample. b) Explain why the change in pH allows the determination of the three ions in this sample.
- If blast furnace slag is activated by NaOH, resulting in the formation of alkali-activated slag (AAS) – what kind of phases form in this system over time? How does the precipitated phase assemblage change with a change in the composition of the precursor slag? What differences exist in these formed phases in AAS systems when compared to blended systems such as OPC-Slag mixtures?A scientist was tasked to extract Fe from an aqueous suspension that contains 106 g of Fe2O3. The following steps detail the transformation of Fe2O3 (aq) to elemental iron: I. Enough sulfur trioxide gas was bubbled to Fe2O3 aqueous suspension to completely yield ferric sulfate. II. Then, 5.00 M nitric acid was added to ferric sulfate yielding an aqueous solution of ferric nitrate. III. Excess magnesium powder was added to the aqueous solution of ferric nitrate precipitating the solid iron ----- a. Write the balanced chemical reaction and the type of chemical reaction for [I], [II], [III]. Do not forget to indicate the states of the reactants and products (s, l, g).(CHOICES: COMBINATION, SINGLE DISPLACEMENT, DOUBLE DISPLACEMENT) b. What is the final mass of iron? Express final answers in 3 significant figures. c. High-concentration HCl is supposed to be added at the last part of the procedure. Briefly state its purpose.An unknown salt X reacts with hot conc. H2SO4 to produce a brown coloured gas which intensifies on addition on copper turnings. On adding dilute ferrous sulphate solution to an aqueous solution of X and then carefully adding conc. H2SO4along the sides of the test tube, a brown complex Y is formed at the interface between the solution and H2SO4. Identify X andY and write the chemical equation involved in the reaction.
- An exhausted zeolite softener was regenerated by passing 100 litres, of NaCl. Solution containing 150 gm per lit. of NaCl. How many lit. of a sample of H2O of hardness 300 ppm can be softened by this softener? (Given at wts. for C = 12, O = 16, Na = 23, CI = 35.5, Ca = 40).An unknown salt X reacts with hot conc. H2SO4 to produce a brown coloured gas which intensifies on addition on copper turnings. On adding dilute ferrous sulphate solution to an aqueous solution of X and then carefully adding conc. H2 SO4 along the sides of the test tube, a brown complex Y is formed at the interface between the solution and H2 SO4. Identify X and Y and write the chemical equation involved in the reaction.Compare the solubility of ferrihydrite (Fe(OH)3) and goethite (FeOOH), with dissolution reactions shown below: Fe(OH)3 + 3H+ <-> Fe3+ + 3H2O FeOOH + 3H+ <-> Fe3+ + 2H2O How much Fe3+ from ferrihydrite would dissolve at pH 2 and 7? How much Fe3+ from goethite would dissolve at pH 2 and 7?