To measure the heat of solution of LiCl a student adds 100.0 grams of water, initially at 15.0 C to a calorimeter. She then adds 10.0 grams of solid LiCl, and stirs to dissolve. The maximum temperature reached by the solution is 35.6 C. A. Calculate the molar heat of solution for LiCl. B. What processes occur when the LiCl is dissolved? Explain which of these processes involves a larger amount of energy. Justify your answer with data.

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Chapter6: Thermochemisty
Section: Chapter Questions
Problem 6.111QP: In a calorimetric experiment, 6.48 g of lithium hydroxide, LiOH, was dissolved in water. The...
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3) To measure the heat of solution of LiCl a student adds 100.0 grams of water, initially at 15.0 C to a calorimeter. She then adds 10.0 grams of solid LiCl, and stirs to dissolve. The maximum temperature reached by the solution is 35.6 C. A. Calculate the molar heat of solution for LiCl. B. What processes occur when the LiCl is dissolved? Explain which of these processes involves a larger amount of energy. Justify your answer with data.
Expert Solution
Step 1

A) Total mass of solution = (100.0+10.0) g

Calculation of heat absorbed by the solution (assuming the specific heat of solution to be same as water):

q=mcT =110.0 g×4.184 J/g°C×(35.6-15.0)°C=9480.944 J=9.481 kJ

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