Two buffers are prepared from the same weak acid and its conjugate base. Using the Henderson-Hasselbalch formula, explain how it is possible for both to have the same pH if the concentration of the acid differs. Which of the two buffers would have the larger buffer capacity?

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Chapter9: Acids, Bases, And Salts
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Problem 9.116E
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Two buffers are prepared from the same weak acid and its conjugate base. Using the Henderson-Hasselbalch formula, explain how it is possible for both to have the same pH if the concentration 
of the acid differs. Which of the two buffers would have the larger buffer capacity?

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