Draw structural formulas for the a B-unsaturated aldehyde or ketone and the lithium diorganocuprate (Gilman reagent) that could beused in a synthesis of the compound shown below.• You do not have to consider stereochemistry.• In cases where there is more than one answer, just give one.If a structure has a copper-lithium bond, draw the lithium ion in a separate sketcher.• Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner.Separate multiple reactants usıng thesign from the drop-down memu.

Answered: Image /qna-images/answer/1ce4270f-b456-4fc0-ba8f-0c607ee33f2d.jpg

Answered: um diorganocuprate (Gilman reagent) th

Science

Chemistry

um diorganocuprate (Gilman reagent) th

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter24: Carboxylic Acids & Derivatives

Section: Chapter Questions

Problem 23CTQ

See similar textbooks

Related questions

Q: Click the "draw structure" button to launch the drawing utility. What product is formed when the…

A: Benedict reagent is used to convert aldehyde or ketones to carboxylic acid. Thus, it acts as an…

Q: Activating 4 Least Activating HIN CH3 Pheno? 13r 1-naphthol anisue Aceteniite Diphenyl etter…

A: Both the activating groups are of different categories. Fastest substrate have strong activating…

Q: Select a Selectea 1 reagent 2 e i

A: Aromatic electrophilic substitution reaction: Aromatic electrophilic substitution reactions are the…

Q: What does the ferric chloride test identify? Is it specific test for eugenol? Why or why not

A: A question based on molecules that is to be accomplished.

Q: Propose a suitable reagent.

A: Organic reactions are those in which organic reactant react to form organic products.

Q: OTS R (strong base) Doubling [B ] doubles rate of rxn.

Q: 1. Explain why litmus paper is used in step 4. Why is blue litmus paper used rather than red litmus…

A: Litmus papers are used to detect whether the given solution is acidic or basic.

Q: Why is Benedict’s reagent blue

A: Benedict's test is the test which shows the presence of aldehydes. This is done using Benedict's…

Q: lumefantrine synthesis

A: Lumefantrine is an antimalarial agent which helps to treat acute malaria.

Q: Draw the products formed when attached dihalide is treated with excess NaNH2.

A: The given compound is a germinal dihalide. Geminal dihalide reacts with strong base like NaNH2 to…

Q: Draw the products formed from nitration of attached compound

A: Given,

Q: How Steric Effects are related with Nucleophilicity ?

A: A nucleophile is a molecule or chemical species that has the capacity to donate an electron pair to…

Q: 20 | Classify each solvent as polar protic, polar aprotic, or neither.

A: Polar solvent which has proton on electronegative atom is polar protic solvent. Polar solvent which…

Q: a. The nitroprusside test is a test for the detection of methyl ketones. What are the reagents used…

Q: (Reagent) Br

A: Given reaction,

Q: .CO2ET d) Но Borohydride Reduction type

A: Sodium borohydride is a relatively selective reducing agent. It is less reactive than Lithium…

Q: Draw the bydrochlaride salt product It CH,-CH-NH=CH3 HCH CH3

A: Given reaction: To draw: The hydrochloride salt product.

Q: Draw the organic products formed in attached reaction

A: Lindlar catalyst have ability to reduce triple bonds to double bonds. It is also like the addition…

Q: strongest Bronsted base?

Q: Draw the organic products formed in attached reaction.

A: The carbon atom that resides at the immediate vicinity to the functional group in a molecule is…

Q: Which is the reduction product of ethyl 3-oxobutanoate with NaBH4 in methanol? (select the correct…

Q: Proindetie Product CN CN NacN DMSO horcachion

A: Nucleophilic substitution occurs when the leaving group is good.

Q: Give the significance of Chromic Acid test? 2. Give the significance of Lucas test? 3. Give the…

A: Chemical tests are so much useful to detect the presence anything that we want. These tests are so…

Q: Draw the organic product of attached reaction.

A: Given,

Q: Question 7 Show the product of treating N-methyl-y-butyrolactam with each reagent:

A: N-methyl γ -butyrolactam is a cyclic amide that contains five atoms in the ring (γ- five-membered…

Q: Draw the organic products formed in attached reaction.

A: Alkenes undergoes addition reaction with HBr. In the presence of peroxides it undergoes…

Q: Draw the products formed from LiAlH4 reduction of attached compound.

A: LiAlH4 (Lithium aluminium hydride) is a reducing agent. It reduces the carbonyl group to an alcohol,…

Q: 1. 2. HCI, A NaO

Q: Draw the organic products formed in attached reaction.

Q: most stable cyanohydrin?

A: A cyanohydrin is a functional group found in organic compounds in which a cyano and a hydroxy group…

Q: Activating 3. Least Activating GOH3 HIM CH3 Pheno? 13r 1-naphthol anisue Aceteniite Diphenyl etler…

A: Solution : An activating group is a group that increases the electron density on the ring like…

Q: Name of Test Sample Reagent Result Sodium bisulfate a. Aldehyde b. Acetone

A: Test used for the detection of carbonyl compounds:

Q: Describe what each reagent does in SDS Page 1. Sodiun dodecyl sulfate 2. Polyacrylamide 3.…

A: The estimation of protein is nowadays carried out by SDS-PAGE methodology. It is an electrophoresis…

Q: Which solvent would be best for promoting SN2? Br + CH;O¯ 90% 10% • A - DMSO • B - Water C - Carbon…

A: Note: As per our guidelines, we are supposed to answer only one question. Please repost the other…

Q: Draw the organic products formed in attached reaction.

A: Alkenes on treatment with bromine (Br2) results in the formation of vicinal dibromides (i.e.…

Q: How would this compound react in ninhydrin test?

Q: select the missing reagents in the pllowing multistep synthesis. Ignore any inorganic byproducts…

Q: Draw the organic product of attached reaction.

Q: C ÇI Na DN

A: The reaction in which one group is substitutes by the other group is known as substitution reaction.…

Q: Which is the reduction product of ethyl 3-oxobutanoate with NaBH4 in methanol? (select the correct…

Q: How many grams of adapalene 0.1 % (w/w) gel is required to make 90 grams of adapalene 0.025 % (w/w)…

Q: Draw a stepwise mechanism for attached reaction.

A: Given reaction,

Q: What starting materials are needed to synthesize attached azo compound?

Question

Draw structural formulas for the a B-unsaturated aldehyde or ketone and the lithium diorganocuprate (Gilman reagent) that could be
used in a synthesis of the compound shown below.
• You do not have to consider stereochemistry.
• In cases where there is more than one answer, just give one.
If a structure has a copper-lithium bond, draw the lithium ion in a separate sketcher.
• Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner.
Separate multiple reactants usıng the
sign from the drop-down memu.

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1 Retrosynthsis and synthesis

VIEW

Step 2 Starting Material and reagent

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 2 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Protection of Groups in Organic Synthesis

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

1. A student chemist in an attempt to synthesise compound B from the aromatic aldehyde. Use the flow equation to answer I and II .Image attached below I)Predict the chemical name of compound B II)What is the reaction name for the chemical transformation of A to B
Enolates are formed by deprotonation of an α-carbon hydrogen. Answer the following questions about enolate formation. In the molecule shown, select the α-carbon hydrogen that would be removed to form an enolate when sodium hydroxide is used as a base. (use photo to answer this question). Then, Draw the thermodynamic enolate that results for the molecule in Part 1. Draw only the enolate resonance form that includes a formal charge on the α carbon. Be sure to indicate that formal charge as well as any lone pair of electrons in your answer.
Explain using words and structures why 2-methoxy-acetophenone is the minor product, and why 3- methoxy-acetophenone is not produced.
1) Based on the Material Safety Data Sheets (MSDS) for the compounds, which of the compounds in this experiment is the most hazardous, and why (you have been given a representative aryl halide rather than all of the alkenes – as the products are all new, there’s not a simple answer to gauge their potential hazard)? 2,3-dihydrofuran,2-Mercaptobenzimidazole,Selectfluor, Dimethylformamide,dichloromethane-methylene chloride.
Write structures for the carbonyl electrophile and enolate nucleophile that react to give the aldol below. You do not have to consider stereochemistry. Draw the enolate nucleophile in its carbanion form. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate multiple reactants using the + sign from the drop-down menu.
What is the purpose of combining nitric acid with sulfuric acid before starting a nitration reaction on an aromatic substrate? Sulfuric acid is necessary to react with nitric acid and form NO2+. Sulfuric acid is a necessary solvent. All aromatic compounds are soluble in sulfuric acid, but insoluble in nitric acid. Sulfuric acid plays no significant role. We are just following the procedure, which calls for sulfuric acid, even though it has no effect. Sulfuric acid is necessary to dilute the nitric acid. Concentrated nitric acid alone reacts too quickly and risks nitrating the substrate a second or third time.
Draw a flowchart showcasing the purification step done for the reaction under basic conditions (the basic reaction of 4-methoxyacetophenone with bleach, sodium hydroxide, and acetone), starting from the crude reaction mixture all the way to the isolated solid product. Assume for this drawing that the reaction was complete, and that none of the intermediates are found in the crude mixture. There may still be however traces of your starting material in the crude mixture, along with any excess reagents
3. For the following compounds, which group on the ring is more strongly activating, and draw the structural formula of the major product formed by nitration.
a. What is the purpose of adding Sodium carbonate to the black tea? You can explain its purpose as a paragraph or by showing the reaction of one phenolic compound reacting with it.b. Do you expect this phenolic compound to be soluble in water or DCM?
Friedel-Crafts Alkylation, based on substituted benzene reaction, including reactivity based on electron donating and withdrawing group and also discuss the possible positions (Ortho, Meta and Para) for the new group. Explain if there is polysubstitution occurs. Keeping the reaction mixture in the ice bath and adding the reagent slowly by continuously stirring is the key point of success.
Draw structural formulas for the α,β-unsaturated aldehyde or ketone and the lithium diorganocuprate (Gilman reagent) that could be used in a synthesis of the compound shown below.
Write the expected product of this reaction: