Use the following character table for tetrahedral point group (To) to answer the following questions: Ta E 8C3 30 6S4 60d Ai +1 +1 +1 +1 +1 x²+y²+z² Az +1 +1 +1 -1 -1 E +2 -1 +2 0 0 (2x²-x²-y², x²-y²) T₁ +3 0 -1 +1 -1 (Rx, Ry, Rz) T₂ +3 0 -1 -1 +1 (x, y, z) (xy, xz, yz) (a) determine the orbitals symmetries of the central metal atom for tetrahedral metal complexes (ML4). (b) draw symmetry labelled molecular orbital (MO) diagram for ML4. Given that the ligand group orbitals (LGOs) symmetries are ai and tz. (c) clearly depict bonding, σ(a) and antibonding, o*(a1) MOs. + (d) use the above (part a) MO diagram to show the electron filling for tetrahedral [Ni(CO)4].
Use the following character table for tetrahedral point group (To) to answer the following questions: Ta E 8C3 30 6S4 60d Ai +1 +1 +1 +1 +1 x²+y²+z² Az +1 +1 +1 -1 -1 E +2 -1 +2 0 0 (2x²-x²-y², x²-y²) T₁ +3 0 -1 +1 -1 (Rx, Ry, Rz) T₂ +3 0 -1 -1 +1 (x, y, z) (xy, xz, yz) (a) determine the orbitals symmetries of the central metal atom for tetrahedral metal complexes (ML4). (b) draw symmetry labelled molecular orbital (MO) diagram for ML4. Given that the ligand group orbitals (LGOs) symmetries are ai and tz. (c) clearly depict bonding, σ(a) and antibonding, o*(a1) MOs. + (d) use the above (part a) MO diagram to show the electron filling for tetrahedral [Ni(CO)4].
Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter13: Introduction To Symmetry In Quantum Mechanics
Section: Chapter Questions
Problem 13.22E: Figure 13.27 shows the structure of the molecule porphine. Figure 13.27 The structure of porphine....
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