Use the following reaction and information to answer a and b. 2ClO2(aq)+2OH-(aq)-->ClO-(aq)+Cl2-(aq)+H2O(l) [ClO2](M) [OH-](M) Initial rate (M/s) 0.060 0.030 0.0248 0.020 0.030 0.00276 0.020 0.090 0.00828 a. What is the order of this reaction in respect to ClO2, with respect to OH-, and the overall order? Assume the rate law has the form rate=k[ClO2]a[OH-]b b. What is the value of the rate constant? Include the units and why the unit make sense.

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter20: Acidity And Pka Of Phenols
Section: Chapter Questions
Problem 11E
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Use the following reaction and information to answer a and b.

2ClO2(aq)+2OH-(aq)-->ClO-(aq)+Cl2-(aq)+H2O(l)

[ClO2](M) [OH-](M) Initial rate (M/s)
0.060 0.030 0.0248
0.020 0.030 0.00276
0.020 0.090 0.00828

a. What is the order of this reaction in respect to ClO2, with respect to OH-, and the overall order? Assume the rate law has the form rate=k[ClO2]a[OH-]b

b. What is the value of the rate constant? Include the units and why the unit make sense.

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