Use the information in the pK, table below to determine which side of the equilibrium is favored for each of the reactions in the second table. acid pKa pKa acid CH2=CH, 45 H2 36 CH3-C=CH 25 19 CH,OH 15.7 10.5 SH -O- 10.0 9 NH 5.3 CH2-S-OH -2 ОН - 2.2 -7.2 Left Right Favored Equilibrium Equation Equal Favored CH3-C=CH ОН + CH3-C=C CH3- + CH,=CH, CH3- CH2=CH ОН CH2=CH2 + CH3- CH,=CH CH3- OH ОН CH,0 + CH,OH

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter4: Polar Bonds, Polar Reactions
Section: Chapter Questions
Problem 45CTQ
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Use the information in the pK, table below to determine which side of the equilibrium is favored for each of the reactions in
the second table.
acid
pK,
acid
pKa
a.
CH2=CH,
H2
45
36
CH3-C=CH
25
19
CH-OH
15.7
10.5
SH
ОН
10.0
5.3
CH3-
ОН
-2
+
OH
CHOH,
- 2.2
-7.2
Left
Right
Favored
Equilibrium Equation
Equal
Favored
CH3-C=CH
CH3-C=C
ОН
CH2
+
CH,=CH2
CH3-
CH,=CH
ОН
+
CH2=CH,
+
CH2-
CH,=CH
CH3
OH
OH
CH-O
+
CH,OH
Transcribed Image Text:Use the information in the pK, table below to determine which side of the equilibrium is favored for each of the reactions in the second table. acid pK, acid pKa a. CH2=CH, H2 45 36 CH3-C=CH 25 19 CH-OH 15.7 10.5 SH ОН 10.0 5.3 CH3- ОН -2 + OH CHOH, - 2.2 -7.2 Left Right Favored Equilibrium Equation Equal Favored CH3-C=CH CH3-C=C ОН CH2 + CH,=CH2 CH3- CH,=CH ОН + CH2=CH, + CH2- CH,=CH CH3 OH OH CH-O + CH,OH
Draw a Lewis structure for each conjugate acid or base. Write in any non-zero formal charges and make sure all atoms in your structures fully satisfy the
octet rule.
molecule 1
conjugate base of molecule 1
m
c+
Н—о:
H
H-C-C-0-H
nd drag to
start drawing a
H
structure.
molecule 2
conjugate base of molecule 2
нн
H
?
N:
Click and drag to
start drawing a
H.
H H
structure.
Transcribed Image Text:Draw a Lewis structure for each conjugate acid or base. Write in any non-zero formal charges and make sure all atoms in your structures fully satisfy the octet rule. molecule 1 conjugate base of molecule 1 m c+ Н—о: H H-C-C-0-H nd drag to start drawing a H structure. molecule 2 conjugate base of molecule 2 нн H ? N: Click and drag to start drawing a H. H H structure.
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