Weak Acid Conjugate Base Ka pK. C20,2- HPO,2- HC204 6.4 x 10-5 4.19 H2PO, 6.2 x 10-8 7.21 HCO3 co,- 4.8 x 10-11 10.32 How many grams of the potassium salt of the weak acid must be combined with how many grams of the potassium salt of its conjugate base, to produce 1.00 L of a buffer that is 1.00 M in the weak base grams potassium salt of weak acid = grams potassium salt of conjugate base =

Weak Acid Conjugate Base Ka pK. C20,2- HPO,2- HC204 6.4 x 10-5 4.19 H2PO, 6.2 x 10-8 7.21 HCO3 co,- 4.8 x 10-11 10.32 How many grams of the potassium salt of the weak acid must be combined with how many grams of the potassium salt of its conjugate base, to produce 1.00 L of a buffer that is 1.00 M in the weak base grams potassium salt of weak acid = grams potassium salt of conjugate base =

Chemistry: An Atoms First Approach

2nd Edition

ISBN:9781305079243

Author:Steven S. Zumdahl, Susan A. Zumdahl

Publisher:Steven S. Zumdahl, Susan A. Zumdahl

Chapter14: Acid- Base Equilibria

Section: Chapter Questions

Problem 4RQ: A good buffer generally contains relatively equal concentrations of weak acid and conjugate base. If...

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A buffer is prepared using the butyric acid/butyrate (HC4H7O2/C4H7O2)acid-base pair. The ratio of acid to base is 2.2 and Ka for butyric acid is1.54105. (a) What is the pH of this buffer? (b) Enough strong base is added to convert 15% of butyric acid to the butyrate ion. What is the pH of the resulting solution? (c) Strong acid is added to the buffer to increase its pH. What must the acid/base ratio be so that the pH increases by exactly one unit (e.g., from 2 to 3) from the answer in (a)?
When 40.00 mL of a weak monoprotic acid solution is titrated with 0.100-M NaOH, the equivalence point is reached when 35.00 mL base has been added. After 20.00 mL NaOH solution has been added, the titration mixture has a pH of 5.75. Calculate the ionization constant of the acid.
A buffer is prepared by dissolving 0.062 mol of sodium fluoride in 127 mL of 0.0399 M hydrofluoric acid. Assume no volume change after NaF is added. Calculate the pH of this buffer.
K4 for acetic acid is 1.7 105 at 25C. A buffer solution is made by mixing 52.1 mL of 0.122 M acetic acid with 46.1 mL of 0.182 M sodium acetate. Calculate the pH of this solution at 25C after the addition of 5.82 mL of 0.125 M NaOH.
A good buffer generally contains relatively equal concentrations of weak acid and conjugate base. If you wanted to buffer a solution at pH = 4.00 or pH = 10.00, how would you decide which weak acidconjugate base or weak baseconjugate acid pair to use? The second characteristic of a good buffer is good buffering capacity. What is the capacity of a buffer? How do the following buffers differ in capacity? How do they differ in pH? 0.01 M acetic acid/0.01 M sodium acetate 0.1 M acetic acid/0.1 M sodium acetate 1.0 M acetic acid/1.0 M sodium acetate
Ammonia gas is bubbled into 275 mL of water to make an aqueous solution of ammonia. To prepare a buffer with a pH of 9.56, 15.0 g of NH4Cl are added. How many liters of NH3; at 25C and 0.981 atm should be used to prepare the buffer? Assume no volume changes and ignore the vapor pressure of water.
What is the pH of a buffer that is 0.175 M in a weak acid and 0.200 M in the acids conjugate base? The acids ionization constant is 5.7 104.
Malonic acid (HO2CCH2CO2H) is a diprotic acid. In the titration of malonic acid w ith NaOH, stoichiometric points occur at pH = 3.9 and 8.8. A 25.00-mL sample of malonic acid of unknown concentration is titrated with 0.0984 M NaOH, requiring 31.50 mL of the NaOH solution to reach the phenolphthalein end point. Calculate the concentration of the initial malonic acid solution. (Sec Exercise 113.)
Each symbol in the box below represents a mole of a component in one liter of a buffer solution; represents the anion (X-), = the weak acid (HX), = H+, and =OH. Water molecules and the few H+ and OH- ions from the dissociation of HX and X- are not shown. The box contains 10 mol of a weak acid, , in a liter of solution. Show what happens upon (a) the addition of 2 mol of OH- (2 ). (b) the addition of 5 mol of OH- (5 ). (c) the addition of 10 mol of OH- (10 ). (d) the addition of 12 mol of OH- (12 ). Which addition (a)-(d) represents neutralization halfway to the equivalence point?
Consider the weak acids in Table 13.2. Which acid-base pair would be best for a buffer at a pH of (a) 3.0(b) 6.5 (c) 12.0