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- Show how you might use the Williamson ether synthesis to prepare each ether. (a) (b)Whats the reason for the girgnard reagent attack that carbon of starting point in this step? a. Bc it gives us desired product b. Due to the sterics c. Bc it is more electrophilic than the other carbon of the starting pointDraw the product when A (TOP) and B (BOTTOM) react together: (Ignore the SOCl2)
- The product of reaction between acetone and bromine (excess) with KOH excess is A. Ch2BrCOCh3 B. ChBr3 C.ChBr2COCH3 D.CBr3COCH3 E.Ch2BrCOCHBr2The following reaction takes place several times faster than the reaction of 2-chlorobutane with HO-: a. Explain the enhanced reaction rate.b. Explain why the OH group in the product is not bonded to the carbon that was bonded to the Cl group in the reactant.For the reaction scheme below: (a) Suggest a reagent X that could be used to accomplish the first step. (b) Draw the curly arrow mechanism for the second step in the scheme.
- Draw a stepwise mechanism for the following Robinson annulation. This reaction was a key step in a synthesis of the steroid cortisone by R. B. Woodward and co-workers at Harvard University in 1951.Which is the major product?a. Ab. Neither product would likely formc. BFriedel-Crafts alkylations usually invariably result in a mixture of products, but Friedel acylations never do. Why? a) none of these b) alkylations require catalyst c) benzene with alkyl groups are more reactive than acylbenzenes d) the reagents used in alkylations are stronger