What is the rationale of maintaining the analyte solution at high pH (~10) in the titration process with EDTA? At this pH, EDTA is at its fully deprotonated form, Y-4. At this pH, EDTA is partially deprotonated with 1 ionizable H+. At this pH, EDTA is at its fully protonated form, H4Y. At this pH, EDTA is partially deprotonated with 2 ionizable H+.

What is the rationale of maintaining the analyte solution at high pH (~10) in the titration process with EDTA? At this pH, EDTA is at its fully deprotonated form, Y-4. At this pH, EDTA is partially deprotonated with 1 ionizable H+. At this pH, EDTA is at its fully protonated form, H4Y. At this pH, EDTA is partially deprotonated with 2 ionizable H+.

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter17: Complexation And Precipitation Reactions And Titrations

Section: Chapter Questions

Problem 17.17QAP

See similar textbooks

Similar questions

A 30-mL portion of a solution containing Ca2+ and Mg2+ was titrated with 28.19 mL of 0.213 M EDTA at pH 10. Another 30-mL aliquot of the same Ca-Mg mixture was treated with NaOH to make the solution strongly alkaline and precipitate Mg(OH)2. This solution was then titrated with the same EDTA solution. What would be the required EDTA volume (in mL) to reach the endpoint of the second aliquot if it was found that there was 0.061 M of Mg2+ in the sample?
An accurately weighed chelometric standard calcium carbonate of 200 mg was used to standardize Disodium Ethylenediaminetetraacetate, using the same procedures set by the monograph. If the molarity of the Disodium EDTA was found to be 0.054 M, what is the final volume of the titrant used?
DETERMINATION OF WATER HARDNESS BY EDTA TITRATION 1. Why is it needed to add a pH 10 buffer to the sample during EDTA titration? 2. What is EDTA and why can it be used to determine the hardness of water?
Please answer this NEATLY, COMPLETELY, and CORRECTLY for an UPVOTE. A 50.00-mL sample of water containing Ca2+ and Mg2+ is titrated with 10.28 mL of 0.01001 M EDTA in an ammonia buffer at pH 10.00. Another 50.00-mL sample is titrated with NaOH to precipitate Mg(OH)2 and then titrated at pH 13.00 with 6.75 mL of the same EDTA solution. Calculate the concentration of CaCO3 and MgCO3 in the sample in ppm.
Which of the following experiments can be described as a displacement titration? A. Calcium in powdered milk is determined by dry ashing a 1.50 g sample and then titrating the calcium with 12.1 mL of 0.008949 M EDTA. B. The Tl in a 9.57-g sample of rodenticide was oxidized to the trivalent state and treated with an unmeasured excess of Mg/EDTA solution. The reaction is Tl3+ + MgY2- -> TlY- + Mg2+ Titration of the liberated Mg2+ required 12.77 mL of 0.03610 M EDTA. C. A 3.650-g sample containing bromide was dissolved in sufficient water to give 250.0 mL. After acidification, silver nitrate was introduced to a 25.00-mL aliquot to precipitate AgBr, which was filtered, washed, and then redissolved in an ammoniacal solution of potassium tetracyanonickelate(II): Ni(CN)42- + 2AgBr(s) -> 2Ag(CN)2- + Ni2+ + 2Br- The liberated nickel ion required 26.73 mL of 0.02089 M EDTA. D. A solution contains 1.569 mg of CoSO4 (155.0 g/ mol) per milliliter. 50.00 mL of 0.007840 M EDTA…
A 50.00 ml aliquot of a solution containing Ca2+ and Mg2+ was buffered at pH 10 and titrated with 0.0499 M EDTA. The endpoint volume was 40.17 ml. A second aliquot of the same mixture was made strongly basic by the addition of NaOH – this causes the Mg2+ to precipitate as Mg(OH)2. The solution was then titrated with the 0.0499 M EDTA and the endpoint volume was found to be 34.70 ml.
Assess the validity of each statement and choose X if the statement is CORRECT, Choose Y if otherwise. 10. Potentiometric methods can be used for end-point detection in EDTA titration of metal ions for which ion electrodes are available 11. Back titrations are useful for determining cations that are able to form stable EDTA complexes. 12. Nitriloacetic acid is an aminopolycarboxylic acid. 13. A ligand that has a single donor group is unidentate such as glycine. 14. Ammonia is a bidentate ligand. 15. The term chelate is derived from a Greek word meaning, toothlike projections
All of the following criteria must be met for a titrimetric analysis to be feasible EXCEPT: Select one: a. Reaction between the standard and analyte must be known. b. There should be a substance for endpoint detection c. Reaction must proceed quantitatively to completion. d. Reaction between the reactants must be slow.
A 50.00 ml aliquot of a solution containing Ca2+ and Mg2+ was buffered at pH 10 and titrated with 0.0418 M EDTA. The endpoint volume was 44.36 ml. A second aliquot of the same mixture was made strongly basic by the addition of NaOH – this causes the Mg2+ to precipitate as Mg(OH)2. The solution was then titrated with the 0.0418 M EDTA and the endpoint volume was found to be 30.02 ml. Calculate the molar concentration of Mg.
Which are TRUE for the use of indicators with dichromate? I Dichromate is orange and changes color to green when reduced. The color change is abrupt enough to serve as an indicator.II The equivalence point for dichromate can be determined using Pt and calomel electrodes.III Dichromate end points are determined using the distinct color changes of diphenylamine sulfonic acid or diphenylbenzidine sulfonic acid indicators.IV In basic solution, the orange dichromate solution changes color to yellow when reduced to chromate anion. The color change is abrupt enough to serve as an indicator. A. I and III B. II and III C. I and IV D. II and IV E. I, II, and IV
Calculate the pZn2+ for solutions prepared by adding 0.00, 5.00, 10.00, 15.00, 20.00, 25.00 and 30.00 mL of 0.0100 M EDTA to 25.00 mL of 0.00250 M Zn2+. Assume that both the Zn2+ and EDTA are 0.0100 M in NH3 to provide a constant pH of 9.0
What is the function of masking agent in EDTA titration?

SEE MORE QUESTIONS

Recommended textbooks for you

Fundamentals Of Analytical Chemistry

Chemistry

ISBN:

9781285640686

Author:

Skoog

Publisher:

Cengage

Fundamentals Of Analytical Chemistry

Chemistry

ISBN:

9781285640686

Author:

Skoog

Publisher:

Cengage

SEE MORE TEXTBOOKS

GET THE APP

About FAQ Academic Integrity Sitemap Document Sitemap

Contact Bartleby Contact Research (Essays)High School Textbooks Literature Guides Concept Explainers by Subject Essay Help Mobile App

GET THE APP

Privacy

Your CA Privacy Rights

Your NV Privacy Rights

About Ads

Manage My Data

bartleby, a Learneo, Inc. business

		At this pH, EDTA is at its fully deprotonated form, Y^-4.
		At this pH, EDTA is partially deprotonated with 1 ionizable H⁺.
		At this pH, EDTA is at its fully protonated form, H₄Y.
		At this pH, EDTA is partially deprotonated with 2 ionizable H⁺.