What mass of the CuCl₂·2H₂O (170.48 g/mol) should be weighed in order to prepare the 250.0 mL Cu(II) (63.546 g/mol) stock solution? What is the mass of Cu in the unknown sample solution? What is the most probable identity of the unknown copper compound, assuming there is 1 mole of Cu per mole of the unknown?

Fundamentals Of Analytical Chemistry
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ISBN:9781285640686
Author:Skoog
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Chapter27: Molecular Fluorescence Spectroscopy
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What mass of the CuCl₂·2H₂O (170.48 g/mol) should be weighed in order to prepare the 250.0 mL Cu(II) (63.546 g/mol) stock solution?

What is the mass of Cu in the unknown sample solution?

What is the most probable identity of the unknown copper compound, assuming there is 1 mole of Cu per mole of the unknown?

A UV-Vis spectrophotometry experiment for the determination of an unknown copper compounds was
carried out by first preparing 250.0 mL of a 100.0 mg/L Cu(II) stock solution using a 100% pure
copper(II) chloride dihydrate, CuCl, 2H20. Appropriate volumes of this stock solution were then
pipetted, added with concentrated ammonia, and diluted in volumetric flasks to come up with 50.00-mL
standard solutions with concentrations of 0, 2.50, 5.00, 10.00, 25.00, and 50.00 mg/L. For the copper
sample, a 50.00-mL solution was prepared by dissolving 3.25 mg of the unknown compound. The
absorbance of the blank, standards, and the unknown sample were then measured at the analytical
wavelength of 610 nm. The relevant data are shown below.
ITII
Solution
Concentration (mg/L)
Volume (mL)
Absorbance
Blank
50.00
0.028
Standard 1
2.50
50.00
0.121
Standard 2
5.00
50.00
0.222
Standard 3
Standard 4
10.00
50.00
0.442
25.00
50.00
0.902
Standard 5
50.00
50.00
1.920
Sample
50.00
0.989
Transcribed Image Text:A UV-Vis spectrophotometry experiment for the determination of an unknown copper compounds was carried out by first preparing 250.0 mL of a 100.0 mg/L Cu(II) stock solution using a 100% pure copper(II) chloride dihydrate, CuCl, 2H20. Appropriate volumes of this stock solution were then pipetted, added with concentrated ammonia, and diluted in volumetric flasks to come up with 50.00-mL standard solutions with concentrations of 0, 2.50, 5.00, 10.00, 25.00, and 50.00 mg/L. For the copper sample, a 50.00-mL solution was prepared by dissolving 3.25 mg of the unknown compound. The absorbance of the blank, standards, and the unknown sample were then measured at the analytical wavelength of 610 nm. The relevant data are shown below. ITII Solution Concentration (mg/L) Volume (mL) Absorbance Blank 50.00 0.028 Standard 1 2.50 50.00 0.121 Standard 2 5.00 50.00 0.222 Standard 3 Standard 4 10.00 50.00 0.442 25.00 50.00 0.902 Standard 5 50.00 50.00 1.920 Sample 50.00 0.989
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