What would be the effect of adding 10 mL of 15 M H₂SO4 rather than 15 mL of 6 M H₂SO4 in the conversion of CuO to CuSO4 ? Comment on how would this would affect the conversion of CuSO4 into copper metal?
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- a) Which ion, Pt(II) or Mn(II), is more likely to form a sulfide in the presence of H2S in water. b) Rationalize your answer with the trends in hard and soft character. c) Give a balance chemical equation from your reaction.A 4.912-g sample of a petroleum product was burnedin a tube furnace, and the SO2produced was collectedin 3% H2O2.Reaction:SO2(g)+H2O2→H2SO4A 25.00-mL portion of 0.00873 M NaOH was introducedinto the solution of H2SO4, following whichthe excess base was back-titrated with 15.17 mL of0.01102 M HCl. Calculate the sulfur concentrationin the sample in parts per million.Describe in details how youwould prepare the following solutions, i. 1L of 0.10M NaoH using sodium hydroxide pellets ii. 1L of 150.0ppm Cu2+ using cu metals. iii. 1L of 4% v\v acetic acid using glacial acetic acid.
- Consider an F M solution of Fe2(SO4)3. Besides H+ and OH−, the known species are Fe3+, Fe(OH)2+, Fe(OH)2+, Fe2(OH)24+, FeSO4+, SO42−, and HSO4−. a) Write the charge balance equation for this solution. b) Which species must be an ion pair, and which comes from acid hydrolysis of Fe3+? Write the balanced acid hydrolysis reaction for the hexa-aquo complex of Fe3+ and report its pKa c) Write two mass balance equations for this solution, one for total iron and one for total sulfate. [How do you think you should handle the species that includes two iron atoms?] Give numerical values for these equations in terms of F.Iron (III) can be separated from other metals, such as chromium, by extraction into ether froma strong aqueous HCl solution. If 50 mL of aqueous HCl containing 0.25 g of iron(III) is treatedwith 150 mL of ether in a one-shot process, how many milligrams of iron is left in the aqueousphase? Use a value of 50 for the distribution ratio.How to prepare 1L of 0.5mM PBS buffer at pH 7 using sodium phisphate monobasic, sodium phosphate diabasic, and sodium chloride...show calculations
- Describe step bystep in details how you would preparethe following solutions: i. 1L of 0.10M NaoH using sodium hydroide pellets. ii. 1L of 150.0ppm Cu2+ using cu metals. iii. 1L of 4% v/v acetic acid using glacial acetic acid.Which member of each pair produces the more acidic aqueoussolution: (a) ZnBr2 or CdCl2, (b) CuCl or Cu(NO3)2,(c) Ca(NO3)2 or NiBr2?Explain the procedure for synthesis of transition metal complexes of hydroxycinnamic acids? For the synthesis of complexes of transition metals with substituted hydroxycinnamic acids, to be specific, p-coumaric acid and ferulic acid
- You are assigned an unknown solution that contains Group III cations. To -1 mL of this solution was added 6 M NH3 the solution was agitated to mix well, and a reddish-brown precipitate with a gelatinous solid clinging to the inner walls of the test tube was observed. The solution was centrifuged and the supernatant was tested for completeness of precipitation by adding an additional drop of 6 M NH3. No cloudiness was observed as the drop of reagent diffused through the solution. The supernatant was then carefully decanted into a clean test tube, labeled (1st solution), and saved for further testing later. The precipitate remaining in the test tube was washed with a small amount of water, centrifuged, and the wash decanted and discarded. To the precipitate was added about 10 drops of 6 M NAOH plus ~1 mL H20 and the test tube was vigorously agitated. The resulting suspension was centrifuged and the supernatant liquid was transferred to another clean test tube and clearly labeled (2nd…What would be observed a. 1 mL of 0.1 N KMnO4, in 4 mL of dilute H2S04 and a few mg of Sodium Metaborate Peroxyhydrate. b. If potassium or sodium perchlorate is substituted for Sodium Metaborate Peroxyhydrate c What is the ph if Sodium Metaborate Peroxyhydrate is dissolved in 5ml of waterA 0.7352g sample of ore containing Fe3+, Al3+ and Sr2+ was dissolved and made up to 500.00 mL. The analysis of metals was performed by a chemistry using complexation volumetry. Initially, an aliquot of 50.00 mL had its pH adjusted to 1.0 and titrated with a standard solution of EDTA 0.02145 mol/L, requiring 6.95 mL to reach the end point. Subsequently, another 25.00 mL aliquot was buffered at pH=5 and titrated with the same EDTA solution, requiring 6.24 mL to reach the end point. Finally, a third aliquot of 25.00 mL was titrated at pH=11, requiring 11.10 mL of the same EDTA solution to complete the titration. Determine the percentage of each of the metals in the sample Given the molar masses: Fe=55.845 g/mol; Al=26.982 g/mol and Sr=87.620 g/mol.