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Which member of each pair produces the more acidic aqueous
solution: (a) ZnBr2 or CdCl2, (b) CuCl or Cu(NO3)2,
(c) Ca(NO3)2 or NiBr2?
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- Which member of each pair produces the more acidic aqueous solution: (a) ZnBr2 or CdCl2, (b) CuCl or Cu(NO3)2, (c)Ca(NO3)2 or NiBr2? Explain.An antacid tablet, weighing 1.25 g, was dissolved in a 1.0 L volumetric flask to allow for determination of calcium carbonate and magnesium carbonate contents. After preparing the solution, an aliquot of 10.0 ml was transferred to an Erlenmeyer flask containing a buffer solution with pH = 10. This aliquot was then titrated with EDTA 0.0040 mol/L and the average volume spent was 15.01 mL. To measure calcium after precipitation After the magnesium was fractionated, a second 10.00 mL aliquot of the stock solution was transferred to an Erlenmeyer flask. and the pH of the present solution was adjusted to a value of approximately 13. In EDTA titration, the volume consumed for observation of the end point was equal to 13.03 mL. Based on this information, (a) Outline the two steps involved, representing the related reactions. (b) Calculate the concentrations of CaCO3 and MgCO3 present in the initial solution. (c) Calculate the masses of CaCO3 and MgCO3 present in the pellet. (d) Calculate the…. An antacid tablet, weighing 1.25 g, was dissolved in a 1.0 L volumetric flask to allow for determination of calcium carbonate and magnesium carbonate contents. After preparing the solution, an aliquot of 10.0 ml was transferred to an Erlenmeyer flask containing a buffer solution with pH = 10. This aliquot was then titrated with EDTA 0.0040 mol/L and the average volume spent was 15.01 mL. To measure calcium after precipitation. After the magnesium was fractionated, a second 10.00 mL aliquot of the stock solution was transferred to an Erlenmeyer flask, and the pH of the present solution was adjusted to a value of approximately 13. In EDTA titration, the volume consumed for observation of the end point was equal to 13.03 mL. Based on this information, a) Outline the two steps involved, representing the related reactions./5 b) Calculate the concentrations of CaCO3 and MgCO3 present in the initial solution./6 c) Calculate the masses of CaCO3 and MgCO3 present in the pellet./6 d) Calculate…
- If the unknown consisted of Co+2, Fe+2, Sr+2, and Ni+2, which cation would completely complex with EDTA first, second, then third during the complexometric determination of magnesium.Consider an F M solution of Fe2(SO4)3. Besides H+ and OH−, the known species are Fe3+, Fe(OH)2+, Fe(OH)2+, Fe2(OH)24+, FeSO4+, SO42−, and HSO4−. a) Write the charge balance equation for this solution. b) Which species must be an ion pair, and which comes from acid hydrolysis of Fe3+? Write the balanced acid hydrolysis reaction for the hexa-aquo complex of Fe3+ and report its pKa c) Write two mass balance equations for this solution, one for total iron and one for total sulfate. [How do you think you should handle the species that includes two iron atoms?] Give numerical values for these equations in terms of F.What is the formula for the weak acid that is responsible for an aqueous solutions of ZnBr2 being acidic?
- An EDTA solution was allowed to react with Pb²⁺ to produce 0.25 M PbY²⁻, 2.67×10⁻⁸ M Pb²⁺ and an excess of 0.10 M at equilibrium (K = 1.1×10⁸). What will be the hydronium ion concentration of the resulting solution?Sometimes it is not possible to indicate the end point of a titration.a) How can one proceed then and what is the name of the type of titration that can be performed? Briefly describe. An example in which this method can be used is in the determination of mercury, which forms strong complexes with EDTA, but for which there is no suitable indicator that can indicate the end point. b) You are given the task of determining the Hg2 + concentration in a sample solution? After adding an excess of EDTA, the sample solution is titrated with a magnesium solution. 20.00 ml of a 0.0452 M EDTA solution was added to 30.00 ml of sample solutionThe excess EDTA was determined by adding 0.0500 M Mg 2+ solution, consuming 4.37 ml to the end point.Explain why colour of KMnO4 disappears when oxalic acid is added to its solution in acidic medium.
- From the value Kf=1.2×10^9 for Ni(NH3)6^2+, calculate the concentration of NH3 required to just dissolve 0.026 mol of NiC2O4 (Ksp = 4×10^−10) in 1.00 L of solution. (Hint: You can neglect the hydrolysis of C2O4^2− because the solution will be quite basic.)0.8153 g of a sample containing Pb(NO3)2 was taken, dissolved in water, and 40.20 mL of 0.06 M EDTA was added. If the excess EDTA was back-titrated with 23.10 mL of 0.02 M EDTA, which of the following is the percentage of Pb(NO3)2? (Pb(NO3)2: 331 g/mol, Pb: 207 g/mol) A. 85,23B. 38.25C. 35.63D. 79.17Given that the Ksp for silver chloride is 1.76 x 10-10, and the Kf of silver(I) diammine cation [Ag(NH3)2 +] is 1.7 x 107, calculate the maximum number of grams of silver chloride that will dissolve in 250.0 mL of a 3.25 M solution of ammonia.