When a solid dissolves in water, heat may be evolved or absorbed. The heat of dissolution (dissolving) can be determined using a coffee cup calorimeter. In the laboratory a general chemistry student finds that when 4.53 g of NH4CIO4(s) are dissolved in 111.60 g of water, the temperature of the solution drops from 24.02 to 21.06 °C. The heat capacity of the calorimeter (sometimes referred to as the calorimeter constant) was determined in a separate experiment to be 1.81 J/°C. Based on the student's observation, calculate the enthalpy of dissolution of NH4CIO4(s) in kJ/mol. Assume the specific heat of the solution is equal to the specific heat of water. AH dissolution kJ/mol

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter4: Energy And Chemical Reactions
Section4.8: Measuring Reaction Enthalpies: Calorimetry
Problem 4.17E
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When a solid dissolves in water, heat may be evolved or absorbed.
The heat of dissolution (dissolving) can be determined using a
coffee cup calorimeter.
In the laboratory a general chemistry student finds that when 4.53
g of NH4CIO4(s) are dissolved in 111.60 g of water, the
temperature of the solution drops from 24.02 to 21.06 °C.
The heat capacity of the calorimeter (sometimes referred to as the
calorimeter constant) was determined in a separate experiment to
be 1.81 J/°C.
Based on the student's observation, calculate the enthalpy of
dissolution of NH4CIO4(s) in kJ/mol.
Assume the specific heat of the solution is equal to the specific heat
of water.
AH dissolution =
kJ/mol
Thermometer
Cardboard or
Styrofoam lid
Nested
Styrofoam cups
Reaction
occurs in
solution.
Transcribed Image Text:When a solid dissolves in water, heat may be evolved or absorbed. The heat of dissolution (dissolving) can be determined using a coffee cup calorimeter. In the laboratory a general chemistry student finds that when 4.53 g of NH4CIO4(s) are dissolved in 111.60 g of water, the temperature of the solution drops from 24.02 to 21.06 °C. The heat capacity of the calorimeter (sometimes referred to as the calorimeter constant) was determined in a separate experiment to be 1.81 J/°C. Based on the student's observation, calculate the enthalpy of dissolution of NH4CIO4(s) in kJ/mol. Assume the specific heat of the solution is equal to the specific heat of water. AH dissolution = kJ/mol Thermometer Cardboard or Styrofoam lid Nested Styrofoam cups Reaction occurs in solution.
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