When a vibrational contribution is taken into account, the heat capacity of a gas increases with the number of atoms in a molecule. Demonstrate whether the heat capacity ratio increases or decreases with the number of atoms in the gas molecule using the CV expression in terms of total contributions.

Modern Physics
3rd Edition
ISBN:9781111794378
Author:Raymond A. Serway, Clement J. Moses, Curt A. Moyer
Publisher:Raymond A. Serway, Clement J. Moses, Curt A. Moyer
Chapter11: Molecular Structure
Section: Chapter Questions
Problem 18P
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When a vibrational contribution is taken into account, the heat capacity of a gas increases with the number of atoms in a molecule. Demonstrate whether the heat capacity ratio increases or decreases with the number of atoms in the gas molecule using the CV expression in terms of total contributions.

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