When analyzing Pb by utilizing ICP-OES, the presence of coexisting elements in the sample solution may lead to the ionization interference. Do you think the use of the following elements: Cs, Na, and Ba can minimize the ionization interference caused by the coexisting elements? Explain. Given that the first ionization energies for these elements are: Cs (3.89 eV), Na (5.14 eV), Ba (5.21 eV), Pb (7.41 eV), respectively.

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter6: Random Errors In Chemical Analysis
Section: Chapter Questions
Problem 6.16QAP
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Inductively coupled plasma-optical emission spectroscopy (ICP-OES) is a quantitative method for
determining trace elements in liquid samples. ICP-OES and other methods of spectrochemical
analysis are typically subject to errors due to the present of interferences. It had been reported that
ICP-OES is significantly affected by spectral interference, but relatively less affected by the
chemical interferences.
(111)
When analyzing Pb by utilizing ICP-OES, the presence of coexisting elements in the
sample solution may lead to the ionization interference. Do you think the use of the
following elements: Cs, Na, and Ba can minimize the ionization interference caused by the
coexisting elements? Explain. Given that the first ionization energies for these elements
are: Cs (3.89 eV), Na (5.14 eV), Ba (5.21 eV), Pb (7.41 eV), respectively.
Transcribed Image Text:Inductively coupled plasma-optical emission spectroscopy (ICP-OES) is a quantitative method for determining trace elements in liquid samples. ICP-OES and other methods of spectrochemical analysis are typically subject to errors due to the present of interferences. It had been reported that ICP-OES is significantly affected by spectral interference, but relatively less affected by the chemical interferences. (111) When analyzing Pb by utilizing ICP-OES, the presence of coexisting elements in the sample solution may lead to the ionization interference. Do you think the use of the following elements: Cs, Na, and Ba can minimize the ionization interference caused by the coexisting elements? Explain. Given that the first ionization energies for these elements are: Cs (3.89 eV), Na (5.14 eV), Ba (5.21 eV), Pb (7.41 eV), respectively.
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