1- The value of the chemical displacement of the axial proton in cyclohexane is less than the equatorial.

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter17: Alcohols And Phenols
Section17.11: Spectroscopy Of Alcohols And Phenols
Problem 19P: When the 1HNMR spectrum of an alcohol is run in dimethylsulfoxide (DMSO) solvent rather than in...
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Q/Reasons for the following:
1- The value of the chemical displacement of the axial proton in cyclohexane
is less than the equatorial.
2- The chemical shift value of o-nitro toluene is higher than that of m-nitro
toluene.
3-The value of the ortho-coupling constant is higher than the para-coupling
constant for aromatic ring protons.
4- When the temperature is lowered below zero when measuring the nuclear
magnetic resonance spectrum of the proton, the proton of the hydroxyl group
pairs with the methylene group of the ethanol compound.
Transcribed Image Text:Q/Reasons for the following: 1- The value of the chemical displacement of the axial proton in cyclohexane is less than the equatorial. 2- The chemical shift value of o-nitro toluene is higher than that of m-nitro toluene. 3-The value of the ortho-coupling constant is higher than the para-coupling constant for aromatic ring protons. 4- When the temperature is lowered below zero when measuring the nuclear magnetic resonance spectrum of the proton, the proton of the hydroxyl group pairs with the methylene group of the ethanol compound.
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