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When Cr(CO)5(PH3) and Cr(CO)5(NH3) are oxidized by one electron: a. What is the change in LFSE? b. Does the C-O distance increase or decrease? Explain briefly. c. When Cr(CO)5(PH3) is oxidized, what is the effect on the Cr-P distance? Explain briefly. d. When Cr(CO)5(NH3) is oxidized, what is the effect on the Cr-N distance? Explain briefly. (T. Leyssens, D. Peeters, A. G. Orpen, J. N. Harvey, New J. Chem. , 2005 , 29 , 1424.)

When Cr(CO)5(PH3) and Cr(CO)5(NH3) are oxidized by one electron: a. What is the change in LFSE? b. Does the C-O distance increase or decrease? Explain briefly. c. When Cr(CO)5(PH3) is oxidized, what is the effect on the Cr-P distance? Explain briefly. d. When Cr(CO)5(NH3) is oxidized, what is the effect on the Cr-N distance? Explain briefly. (T. Leyssens, D. Peeters, A. G. Orpen, J. N. Harvey, New J. Chem. , 2005 , 29 , 1424.)

Chemistry: The Molecular Science
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds
Section: Chapter Questions
Problem 125QRT: Two different compounds are known with the formula Pd(py)2Cl2, but there is only one compound with...
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When Cr(CO)5(PH3) and Cr(CO)5(NH3) are oxidized by one electron: a. What is the change in LFSE? b. Does the C-O distance increase or decrease? Explain briefly. c. When Cr(CO)5(PH3) is oxidized, what is the effect on the Cr-P distance? Explain briefly. d. When Cr(CO)5(NH3) is oxidized, what is the effect on the Cr-N distance? Explain briefly. (T. Leyssens, D. Peeters, A. G. Orpen, J. N. Harvey, New J. Chem. , 2005 , 29 , 1424.)
Transcribed Image Text:When Cr(CO)5(PH3) and Cr(CO)5(NH3) are oxidized by one electron: a. What is the change in LFSE? b. Does the C-O distance increase or decrease? Explain briefly. c. When Cr(CO)5(PH3) is oxidized, what is the effect on the Cr-P distance? Explain briefly. d. When Cr(CO)5(NH3) is oxidized, what is the effect on the Cr-N distance? Explain briefly. (T. Leyssens, D. Peeters, A. G. Orpen, J. N. Harvey, New J. Chem. , 2005 , 29 , 1424.)
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