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- Hexanoic acid was added to an immiscible biphasic solvent system, water and CCl4 at 20.0OC and the equilibrium concentrations of hexanoic acid were determined to be 3.66 g/L in H2O and 67.0 g/L in CCl4. Caluclate the distrubution coeffiecent (D2) of hexanoic acid in water with respect to CCl4.What volume (mL) of the prepared low alcoholic elixir is needed if the prescription requires 120 mL of an alcoholic elixir with 35% v/v alcoholic strength? Low alcoholic elixir alcoholic strength: 20% Low Alcoholic ElixirCompound Orange Spirit 10mLAlcohol 100mLGlycerin 200mLSucrose 320gPurified water, qs ad 1000mL High alcoholic elixir alcoholic strength: 79% High Alcoholic ElixirCompound Orange Spirit 4mLSaccharin 3gGlycerin 200mLAlcohol, qs ad 1000mL a 30.51 mL b 119.39 mL c 89.49 mL d 30.61 mL(a) Water in vadose zone contains chlorobenzene of concentration 40 mg/L. What is the equilibrium concentration soil air in contact with this solution? (b) An aquifer with porosity 0.3 has distribution coefficient of TCE as 100 L/kg. What fraction of TCE is in aqueous phase and sorbed phase of the soil?
- Carboxylic acids, including fatty acids and benzoic acids, are often present inboth municipal and industrial effluents. Describe a sample preparationcombined with GC method for identification and determination of carboxylicacids in raw wastewater at ppb (µg L-1) level. Point out a suitable samplepreparation technique and GC conditions in details and give justifications foryour choiceWhat is the Molecular weight of a certain volatile liquid which is placed in 225 g flask which has total capacity volume of 252.17 mL. After the liquid was heated to 96.7 oC the gass volatilized and the weight of the flask measure 227.33g. What is the could be the MW of the volatile sample?Carbonic anhydrase of erythrocytes (Mr 30,000) has one of the highest turnover numbers known. It catalyzes the reversible hydration of CO2:This is an important process in the transport of CO2 from the tissues to the lungs. If 10.0 μg of pure carbonic anhydrase catalyzes the hydration of 0.30 g of CO2 in 1 min at 37 °C at Vmax , what is the turnover number (kcat) of carbonic anhydrase (in units of min −1 )?
- 1) Commercial fuming Sulphuric acid (Oleum-H2S2O6) is 99.9% solution. Please convert it into molarity.2) Find out the Volume (dm3) of product (gas) at RTP when 0.58 M, 150 mL NaOH (aq.) reacts with 350 mL, 0.25 NH4Cl.Suppose you have a soil that is made up of 10% organic matter with CEC = 200 cmol/kg, 40% kaolinitewith CEC = 10 cmol/kg, and 50% vermiculite with CEC = 100 cmol/kg.1- Calculate the overall CEC of the soil by taking a weighted average of the three soil components.2- What percentage of the overall CEC is contributed by the organic matter? How does that numbercompare to the 10% of the soil itself that is organic?One litre of a saturated aqueous solution of Ag2SO4 (MW = 311.79 g mol- 1) at 25 °C is evaporated to dryness. 4.844 g of Ag2SO4 residue was produced. What is the solubility product (Ksp)?
- What is ΔSsurr for a reaction at 28.6 °C with ΔHsys = 38.9 kJ mol-1 ? Express your answer in J mol-1 K-1 to at least two significant figures.Express [O3] = 2.0 x 1012 molecules cm-3 as a volume mixing ratio (ppbv) at 25 ºC, 1 atm.A 100 g soil containing 20% smectitie mineral matter was mixed with 150 mL solution containing 0.10 M Pb. CEC of pure smectitie is 110 emol(+)/kg. CEC of the soil (cmol(+)/kg) is: