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(a) Water in vadose zone contains chlorobenzene of concentration 40 mg/L. What is the equilibrium
concentration soil air in contact with this solution?
(b) An aquifer with porosity 0.3 has distribution coefficient of TCE as 100 L/kg. What fraction of TCE is in
aqueous phase and sorbed phase of the soil?
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- Suppose you have a soil that is made up of 10% organic matter with CEC = 200 cmol/kg, 40% kaolinitewith CEC = 10 cmol/kg, and 50% vermiculite with CEC = 100 cmol/kg.1- Calculate the overall CEC of the soil by taking a weighted average of the three soil components.2- What percentage of the overall CEC is contributed by the organic matter? How does that numbercompare to the 10% of the soil itself that is organic?The carbon dioxide from the combustion of 1.50 grams of C2H6 is collected over water at 25 degrees Celsius. The pressure of CO2 in the collection flask is 746 mm Hg, and the volume is 2000.00 mL. How much of the CO2 formed apparently dissolved in the water of the pneumatic trough?A stock solution of potassium permanganate (KMn04) was prepared by dissolving 13.0g KMn04 with DI in a 100ml volumetric flask and diluting to the calibration mark. Determine the molarity of the solution.
- Electrolytic manganese dioxide can be prepared from manganese carbonate ore by crushing,milling and leaching the ore in sulphuric acid. Manganese sulphate is crystallised from thesolution, redissolved and electrolysed to give the manganese dioxide.If the crystallisation were performed in a 30m3 tank and the concentration of the solutionentering the tank were 160 grams per litre and left the tank at 40 grams per litre, how muchMnSO4.5H2O would be produced.A 0.512 g sample of a commercial phosphate detergent was ignited at a red heat to destroy the organic matter. The residue was taken up in hot HCl, which converted the P to H3PO4. The phosphate was precipitated as MgNH4PO4.6H2O by addition of Mg2+ followed by aqueous NH3. After being filtered and washed the precipitate was converted to Mg2P2O7 by ignition at 1000 0C and the residue weighed 0.1151g. (a) What is the Gravimetric Factor to convert Mg2P2O7 to P? (b) Calculate the percent P in the sample could you type it out pleaseBy pipet, 15.00ml of the stock solution of potassium permanganate (KMn04) that was prepared by dissolving 13.0g KMn04 with DI H20 in a 100.00ml volumetric flask, diluting to the calibration mark was then transferred to a 50.00ml volumetric flask and diluted to the calibration mark. Determine the molarity of the resulting solution.
- 1. Sodium carbonate is recovered as decahydrate from 1000kg of 5% solution of sodium carbonate in water. If it is desired that 95% of Na2CO3 is to be recovered as decahydrate by cooling to 278 K, determine the following: a) the mass of water evaporated (b) the mass of crystals obtained (Na2CO3 ∙ 10H2O). The solubility of Na2CO3 in water at 278K is 9.0% (weight) 2. A copra batch contains 44% oil and is to be extracted with n-hexane. The extracted meal contains 0.07 kg of oil/kg oil free matter and the mass fraction of n-hexane in it is 0.05. The extract contains 49% n- hexane. If 10,000 kg of copra are to be processed, how many kg of n-hexane are required and the determine the amount of extract. 3. Absorption of sulphur dioxide is carried out in a packed tower. Gas containing 14.8% sulphur dioxide and the rest inert gases enters the tower while the leaving gases contains 1% sulphur dioxide. Water flows at the rate of 1m3/min. The tower handles 7380 m3/hr of gas at 303K and 1 bar. Find…A mixture of methane and air is capable of being ignited only if the mole percent of methane is between 5% and 15%. A mixture containing 9.0 mole% methane in air flowing at a rate of 7:00 x 102 kg/h is to be diluted with pure air to reduce the methane concentration to the lower flammability limit. Calculate the required flow rate of air in mol/h and the percent by mass of oxygen in the product gas. (Note: Air may be taken to consist of 21 mole% O2 and 79% N2 and to have an average molecular weight of 29.0.)An impure sample of Na3PO3 weighing 0.1392 g was dissolved in 25 mL of water. A solution containing 50 mL of 3% w/v mercury(II) chloride, 20 mL of 10% w/v sodium acetate, and 5 mL of glacial acetic acid was then prepared. The solution containing the phosphite was added dropwise to the second solution, oxidizing PO3^3– to PO4^3– and precipitating Hg2Cl2. After digesting, filtering, and rinsing, the precipitated Hg2Cl2 was found to weigh 0.4320 g. Report the purity of the original sample as %w/w Na3PO3. Moles Na3PO3 = moles Hg2Cl2
- A 100 g soil containing 20% smectitie mineral matter was mixed with 150 mL solution containing 0.10 M Pb. CEC of pure smectitie is 110 emol(+)/kg. CEC of the soil (cmol(+)/kg) is:It is desired to determine the molecular weight of an organic compound known to be volatile. For this, a glass balloon with a full volume of 152 mL is weighed and the weighing result is recorded as 215 g. Then, the organic compound that is desired to have some molecular weight in liquid form is added into the balloon and evaporated in a water bath until dryness. After the steam temperature is measured as 90 °C, the balloon is left to cool and the organic compound in the balloon condenses again. The balloon is then weighed again and recorded as 215,367g. Find the molecular weight of this organic compound since the pressure of the environment where the experiment is performed is 700 mmHg.Note: Express % strength with 4 decimal places. For ratio strength, state the volume only% Astelin nasal spray contains 0.1% azelastine hydrochloride and 125 mcg/mL of benzalkonium chloride as a preservative. A container is capable of delivering 200 metered sprays of 0.137 mL each. The percent concentration of benzalkonium chloride in the preparation is _______%, which is equivalent to a ratio strength of 1 in _____ w/v.