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- 2-bromopentane, when treated with alcoholic KOH yields a mixture of three alkenes A, B and C. Identify A, B and C. Which is predominant?Give the major product for the reaction. (CH3)2CHCHBrCH3 + -OC(CH3)3Q2. What are the products of the following reactions? Q3. 2-Bromopentane, when treated with alcoholic KOH yields a mixture of three alkenes A, B and C. Identify A, B and C. Which is predominant?
- What is the major product formed when 3-methyl-1-butene is treated with Hg(C2H3O2)2 in a THF/ethanol mixture followed by NaBH4 in base?Oximene and myrcene, two hydrocarbons isolated from alfalfa that have the molecular formula C10H16, both yield 2,6- dimethyloctane when treated with H2 and a Pd catalyst. Ozonolysis of oximene forms (CH3)2C = O, CH2 = O, CH2(CHO)2, and CH3COCHO. Ozonolysis of myrcene yields (CH3)2C = O, CH2 = O, (two equiv), and HCOCH2CH2COCHO. Identify the structures of oximene and myrcene.Account for the regioselectivity and stereoselectivity observed when 1-methylcyclopentene is treated with reagent Q.Hg(OAc)2 in H2O
- Compound X, C7H15Cl, is a chiral product of the radical chlorination of 2-methylhexane.Base-promoted E2 elimination of X gives a single product.What is the structure of X?Write the structure of the compound E,E-2,4-Hexadien-1-ol and label each non-equivalent carbon with a letter, A,B,C..When buta-1,3-diene (CH2 = CH – CH = CH2) is treated with HBr, two constitutional isomers are formed, CH3CHBrCH = CH2 and BrCH2CH = CHCH3. Draw a stepwise mechanism that accounts for the formation of both products.
- Predict the product C of the following reaction below and briefly explain youranswer.[PtCl3(C2H4)]¯ + NH3 → CThe sex attractant given off by the common house fly is a simple alkene named muscalure,{CH3 (CH2)7CH=CH (CH2)19CH3}. What products would you expect to obtain if muscalurewere treated with: iii) Ozone in the presence of acetic acid iv) KMnO4 in the presence of KOH and water1-Methylcyclohexene is treated with water in the presence of sulfuric acid to give an unknowncompound with the molecular formula C7H14O. Draw the reaction.