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- For each reaction, decide whether substitution or elimination (or both) is possible, andpredict the products you expect. Label the major products. chlorocyclohexane + NaOC(CH3)3 in (CH3)3COHThe replacement of CH3OH to dimethyl sulfoxide, DMSO (CH3)2S=O) as a solvent in the substitution reaction below results in what?When 3-methyl-1-butene is reacted with 9-borabicyclo[3.3.1]nonane, the "1-ol" product is formed. What is the detailed reactin scheme for the transformation? Describe the purification procedure.
- Oxidation of Butanol -1 in KMnO4/H+ will produce-------------. a.Butanoic Acid b.Butanal c.Pentanoic acid d.Butene -21-ethylcycloheptene + cold, dilute KmnO4Explainwhythefollowingdeuterated1-bromo-2-methylcyclohexaneundergoes dehydrohalogenation by the E2 mechanism, to give only the indicated product. Two other alkenes are not observed.
- Q7 Consider the reaction, where the alkane shown is subjected to radical bromination at 25 °C. Br₂ light Describe the major monobromination product. productd. Reaction with CH3MgI (excess), ether; then H+/H2O e. Reaction with LiAlH4, ether; then H+/H2O f. Reaction with DIBAL (diisobutylaluminum hydride), toluene, low temperature; then H+/H2O(a) What happens when CH3—O—CH<sub3 is heated with HI?(b) Explain mechanism for hydration of acid catalyzed ethene :CH2 = CH2 + HzO CH3—CH,—OH
- Please identify priorities of functional groups and name following molecules based on thier stereochemistry as R or SElimination occurs when (Z)-3-bromohex-3-ene is treated with NaNH2. Under the same conditions, 1-bromocyclohexeneundergoes elimination much more sluggishly. Explain whyWhen (CH3CH2)3CBr is added to CH3OH at room temperature, the product is(CH3O)C(CH2CH3)3. Propose a mechanism(s) for the reactions leading to theseproducts and use curved arrows to show the movement of electrons.