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- Rank the set of substituents below in order of priority according to the Cahn-Ingold-Prelog sequence rules. 1 = highest priority. (a) —CO₂H | (b) —CO2CH3 (c)-CH₂OH(d)-CH3Solve the se for the missing parts to mouce it complete. Cive all the possible if es produt. stoate which is major there is one. .F Ma a EtO b) con HNO3 AlCl3 c) NC Cl2/FeCls ? Mé fuming Hy SOu so ? NO2 e) CottsO Na モ401. Draw the structure of the major products of the following reactions -OH (1) DMSO, (COCI)2 (2) EtgN A. H,CrO, В. (1) KMNO,, HO", A OH (2) H,O* С.
- L. ca tramolecular D-A 2. then retro-D-A (loss Co,) 4. CO, Me cntremolecular かA 5. intramaka cular NO 3+2] N-OH NaOcl 6. entramalecular [312) CN 7. CNWhy structure belongs to this IR and why?(d) Explain, why [Co(H,O)62+ is pale pink 2 max = 10 cm mol-) la12- whereas C C1 is deep'blue (Emax = 600 cm mol). (3) %3D max Predict the possible transitions in cach case.
- Prediga los productos de las siguientes reacciones. (a) éter sec-butil isopropflico + HBr conc., calor (c) éter di-n-butflico + NaOH conc. caliente (e) etoxibence no + HI conc., calor (b) 2-etoxi-2-metilpentano + HBr conc., calor (d) éter di-n-butllico + Na metálico (1,2-epoxihexano+H*,CH,OH3. Caffeine has a structure given by : CH3 H;C What IR peaks/bands would you expect based on the topics covered in class for this molecule (you can ignore the Nitrogen bond peaks for now) also sketch the spectra with peaks you expect.The molecular formula of unknown compound B is C10H16.Quantitative brominationof a 0.473-g sample of compound Brequired 48.22mL of a 0.216MBr2/CCl4to produce a color change. How many rings and pi bonds does compound Bcontain?Include any explanations/calculations to justify your answers.