Which of the following compounds would react most vigorously with liquid bromine when no light is present? A) cyclohexane B) Hexane C) benzene D) hex-2-ene
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- When toluene is treated with sulfuric and nitric acids under special conditions, three nitro (NO2) groups are substituted for hydrogens at the 2, 4 and 6 positions on the ring (the next section discusses why the 2, 4, and 6 positions are substituted). The product is a highly explosive substance called 2,4,6-trinitrotoluene. This subastance is commonly known by a three letter name. What is it?H8. Organic chemistry Text answers and (descriptive structures and / or reaction mechanisms). Explain the chemistry of the carbonyl group (direct addition of nucleophiles and addition with elimination)Which of the following reactions of benzene requires a Lewis acid? a Bromination b FC Alkylation c FC acylation d all of the above
- Reaction of propene (above) with HBr might, in principle, lead to a mixture of two alkyl bromide addition products. Name these two alkyl bromides.what is the compound that most easily reacts with bromine in addition? a) CH4 b) C2H2 c) C3H8 d) C4H10If 1-bromopentane is heated in acetone containing NaOH, what is the alkane produced? Draw and explain the step-by-step mechanism of the production of the compound
- Propene reacts with hydrogen bromide (HBr) at room temperature to produce, 1-bromopropane and 2-bromopropane. H2C=CHCH3 + HBr → CH2(Br)CH2CH3 + CH3CH(Br)CH3 Draw out the reaction mechanism of the reaction between propene and hydrogen bromide to produce 2-bromopropane. Use curly arrows to show the movement of electrons. The description should be detailed and must include the type of bond fission that takes place. You may sketch and insert suitable diagrams to aid your description if you wish. Referring to the above mechanism, explain why two products are formed in the reaction between propene and hydrogen bromide?Why does (Z)-2-butene react faster than (E)-2-butene?Give reasons for the following :(i) Ethyl iodide undergoes SN2 reaction faster than ethyl bromide.(ii) (±) 2-Butanol is optically inactive.(iii) C—X bond length in halobenzene is smaller than C—X bond length in CH3—X.
- 1. Using Br2 in C2H4Br2 will result in HBr and ______. a. C2H3Cl3 b. C2H4Cl3 c. C2H2Cl3 d. none of the above 2. How many halogenation are posible in propane? a. 3 b. 8 c. 6 d. 10 3.Sulfonation of pentane will result in ________ and water. a. C5H11SO3H b. C5H12SO3H c. C5H14SO3H d. none of the above 4.Nitration of hexane will result in ________ and water. a. C6H13SO3H b. C6H15NO2 c. C6H13NO2 d. C6H14NO2 5.How many moles of O2 in heating a C12H26 (dodecane) a. 27 b. 37 c. 24 d. none of the aboveChemical reactions:(1) Color KmnO4 and Cylohexane ____________________(2) Color KmnO4 and 2-methyl-Cylohexanol ____________________ (3) Color KmnO4 and Cylohexene or Limonene ____________________ (4) Color KmnO4 and Product Mixture ____________________Which of the following is most soluble in basic medium? a. cyclopropane b. 1,3-cyclobutadiene c. 1,3-cyclopentadiene d. benzene
